tetraethylammonium pentacarbonyl(triphenylphosphite)vanadate

Base Information

• Chemical Name: tetraethylammonium pentacarbonyl(triphenylphosphite)vanadate
• CAS No.: 79152-75-3
• Molecular Formula: C₈H₂₀N*C₂₃H₁₅O₈PV
• Molecular Weight: 631.536
• Mol file: 79152-75-3.mol

Synonyms:

Chemical Property of tetraethylammonium pentacarbonyl(triphenylphosphite)vanadate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetraethylammonium pentacarbonyl(triphenylphosphite)vanadate

There total 2 articles about tetraethylammonium pentacarbonyl(triphenylphosphite)vanadate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

triphenyl phosphite (101-02-0) + tetraethyl ammonium pentacarbonyl (triphenyl phosphine) vanadat (10170-61-3) → tetraethylammonium pentacarbonyl(triphenylphosphite)vanadate (79152-75-3)

Guidance literature:

In tetrahydrofuran; under N2 or Ar, ca. 20-fold excess of P(OPh)3, 68°C; detected by IR; Kinetics;

Reference yield:

triphenyl phosphite (101-02-0) + tetraethylammonium (dimethylsulfoxide)pentacarbonylvanadate (96445-01-1) → tetraethylammonium pentacarbonyl(triphenylphosphite)vanadate (79152-75-3)

Guidance literature:

In tetrahydrofuran; soln. of complex in THF was treated with an excess of phosphite and stirred for 12 h at room temp. (N2);

upstream raw materials:

triphenyl phosphite

tetraethyl ammonium pentacarbonyl (triphenyl phosphine) vanadat

tetraethylammonium (dimethylsulfoxide)pentacarbonylvanadate

Refernces

• 1、 Darensbourg, Marcetta Y.,Hanckel, John M.. "Site-specific ion fairing of monosubstifuted vanadium carbonylaies, LV(CO)5-". . p. 82 - 87. Retrieved 2008/10/08.