[Zn(1,4-benzenedicarboxylate)(H₂O)]*DMF

Base Information

• Chemical Name: [Zn(1,4-benzenedicarboxylate)(H₂O)]*DMF
• CAS No.: 213275-65-1
• Molecular Formula: C₃H₇NO*C₈H₄O₄*H₂O*Zn
• Molecular Weight: 320.617
• Mol file: 213275-65-1.mol

Synonyms:

Chemical Property of [Zn(1,4-benzenedicarboxylate)(H₂O)]*DMF

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Zn(1,4-benzenedicarboxylate)(H₂O)]*DMF

There total 6 articles about [Zn(1,4-benzenedicarboxylate)(H₂O)]*DMF which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

terephthalic acid (100-21-0) + N,N-dimethyl-formamide (68-12-2,33513-42-7) + zinc(II) oxide → [Zn(1,4-benzenedicarboxylate)(H2O)]*DMF (213275-65-1)

Guidance literature:

With H₂O; In neat (no solvent); grinding C6H4(COOH)2 with ZnO and DMF (with H2O content of 10 % v/v) for30 min; detd. by XRD;

DOI:10.1002/anie.200906965

Reference yield: 99.0%

hydrozincite + terephthalic acid (100-21-0) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → [Zn(1,4-benzenedicarboxylate)(H2O)]*DMF (213275-65-1)

Guidance literature:

In neat (no solvent); grinding C6H4(COOH)2 with 2ZnCO3*3Zn(OH)2 and DMF for 20 min; H. Li et al., J. Am. Chem. Soc. 1998, 120, 8571; detd. by XRD;

DOI:10.1002/anie.200906965

Reference yield:

zinc(II) nitrate hexahydrate + terephthalic acid (100-21-0) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → [Zn(1,4-benzenedicarboxylate)(H2O)]*DMF (213275-65-1)

Guidance literature:

With triethylamine; In N,N-dimethyl-formamide; toluene; slow diffusion of Et3N and toluene into soln. of Zn-salt and acid at room temp.; elem. anal.;

DOI:10.1021/ja981669x

upstream raw materials:

terephthalic acid

N,N-dimethyl-formamide

Zn(1,4-benzenedicarboxylate)(H₂O)

[zinc(1,4-benzenedicarboxylate)(H₂O)2]

Downstream raw materials:

[zinc(1,4-benzenedicarboxylate)(H₂O)2]

Zn(1,4-benzenedicarboxylate)(H₂O)

Refernces

• 1、 Tang, Panjuan,Jia, Chunmei,Jiang, Yujie,Gong, Wei,Cao, Xiaocong,Yang, Junyi,Yuan, Wenbing. "Reactivity Studies of Metal–Organic Frameworks under Vapor-Assisted Aging: Structural Interconversions and Transformations". supporting information. p. 5617 - 5622. Retrieved 2016/12/26.