dibromo(2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)iron(III)

Base Information

• Chemical Name: dibromo(2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)iron(III)
• CAS No.: 1264258-84-5
• Molecular Formula: C₂₉H₄₁Br₂FeN₂
• Molecular Weight: 633.313
• Mol file: 1264258-84-5.mol

Synonyms:

Chemical Property of dibromo(2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)iron(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dibromo(2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)iron(III)

There total 1 articles about dibromo(2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)iron(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Na(CH(C(Me)N(2,6-diisopropylphenyl))2)*2tetrahydrofuran + iron (III) bromide (10031-26-2) → dibromo(2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)iron(III) (1264258-84-5)

Guidance literature:

In toluene; (N2); stirring 1:1 mixt. of reaction of iron compd. and ketiminate deriv. in toluene at room temp. for 2 h; evapn., extn. (pentane), filtration through celite, concg., keeping at -30°C for 24 h, isolation of crystals, elem. anal.;

DOI:10.1021/ic102300d

Reference yield:

[Fe(NO)2(CH(C(Me)N(2,6-diisopropylphenyl))2)] + dibromo(2,4-bis(2,6-diisopropylphenylimido)pent-3-yl)iron(III) (1264258-84-5) → [FeBr(NO)(CH(C(Me)N(2,6-diisopropylphenyl))2)] (1264258-80-1)

Guidance literature:

In not given; (N2); mixing solns. of iron compd., keeping at room temp. for 24 h; IR monitoring;

DOI:10.1021/ic102300d

upstream raw materials:

iron (III) bromide

Downstream raw materials:

[FeBr(NO)(CH(C(Me)N(2,6-diisopropylphenyl))2)]

Refernces