102-87-4 Usage
Description
TRIDODECYLAMINE, also known as tridodecylamine (CAS# 102-87-4), is a tertiary fatty amine characterized by its clear, slightly yellow liquid appearance. It is soluble in organic solvents and insoluble in water, making it a versatile chemical intermediate. Its combustible nature should be taken into account when handling and using it in various applications.
Uses
Used in Chemical Intermediates:
TRIDODECYLAMINE is used as a chemical intermediate for its ability to react with other compounds, facilitating the synthesis of various chemical products.
Used in Metal Complexes:
TRIDODECYLAMINE is used in the formation of metal complexes, where it can interact with metal ions to create stable, useful compounds.
Used in Embedded Telemetry Systems:
TRIDODECYLAMINE is used as a component in the preparation of embedded telemetry systems for potentiometric sensors, contributing to the development of advanced sensor technologies.
Used in Gemini Cationic Surfactant-Based Ionic Liquids:
TRIDODECYLAMINE is used in the preparation of gemini cationic surfactant-based ionic liquids, which have potential applications in various fields due to their unique properties.
Used in Extraction Processes:
TRIDODECYLAMINE is used as an extraction agent for various substances, including picolinic acid, citric acid, silver, mercury, selenium, zinc, cobalt, iron, and succinic acid from aqueous solutions. It is used in conjunction with various organic solvents as diluents to enhance the extraction process.
Used in Wastewater Treatment:
TRIDODECYLAMINE is used in the recovery of Remazol Red 3BS (R3BS) dye from wastewater through the emulsion liquid membrane (ELM) process, where it serves as the carrier agent, helping to remove dyes and pollutants from wastewater.
Used in Synthesis of Gemini Surfactant-Based Ionic Liquids:
TRIDODECYLAMINE is used in the synthesis of gemini surfactant-based ionic liquids by reacting with dibromo alkanes, leading to the formation of novel ionic liquids with potential applications in various industries.
Purification Methods
Distil tridodecylamine under high vacuum and N2, and store it in the absence of CO2. It can be crystallised from 95%EtOH/*C6H6 at low temperature under vacuum. The hydrochloride has m 78-79o. [Ra et al. J Org Chem 9 259 1944, Beilstein 4 III 413, 4 IV 801.]
Check Digit Verification of cas no
The CAS Registry Mumber 102-87-4 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 2 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 102-87:
(5*1)+(4*0)+(3*2)+(2*8)+(1*7)=34
34 % 10 = 4
So 102-87-4 is a valid CAS Registry Number.
InChI:InChI=1/C36H75N/c1-4-7-10-13-16-19-22-25-28-31-34-37(35-32-29-26-23-20-17-14-11-8-5-2)36-33-30-27-24-21-18-15-12-9-6-3/h4-36H2,1-3H3
102-87-4Relevant articles and documents
Selectivity control in substituted fatty amines synthesis from esters or nitriles in the presence of bifunctional catalysts
Barrault,Brunet,Suppo-Essayem,Piccirilli,Guimon
, p. 1231 - 1238 (1994)
Copper chromite-type catalysts, supported by alumina or graphite and promoted with barium, were used for the one-step synthesis of tertiary fatty amines [R2NCH3 or RN(CH3)2] from ester, acid or nitrile and ammonia, methanol and hydrogen. The surface composition of the catalysts, studied by X-ray photoelectron spectroscopy and by adsorption experiments, showed that there was a correlation between selectivity and the presence of a well-dispersed CuCrO2 phase, stabilized with barium. Moreover, the elements influencing the stability of the copper catalysts were also studied, and the promoter or/and the support increased the copper surface area and the stability of the catalyst in the presence of water or ammonia.
Alkyl substituent effect on the polarity of phenols-tri-n-alkylamine complexes
Pawelka, Zbigniew,Zeegers-Huyskens, Therese
, p. 1012 - 1018 (2007/10/03)
The formation constants and the dipole moments of the H-bonded adducts of 1:1 and 2:1 stoichiometries formed between three different phenols (phenol, 2,4,6-trichlorophenol, and 2,4-dinitrophenol) and different tri-n-alkylamines are determined in solvents
Amine oxide process
-
, (2008/06/13)
A process for accelerating the oxidation of tert-amines by hydrogen peroxide by conducting the reaction in the presence of an ascorbic acid promoter.