103559-17-7

Basic information

• Product Name: Silane, [chloro[(4-chlorophenyl)thio]methyl]trimethyl-
• CAS NO: 103559-17-7
• Molecular Formula: C10H14Cl2SSi
• Molecular Weight: 265.279
• Mol File: 103559-17-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, [chloro[(4-chlorophenyl)thio]methyl]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [chloro[(4-chlorophenyl)thio]methyl]trimethyl-(103559-17-7)
• EPA Substance Registry System: Silane, [chloro[(4-chlorophenyl)thio]methyl]trimethyl-(103559-17-7)

Safety Data

• Hazardous Substances Data: 103559-17-7(Hazardous Substances Data)

Upstream product

• 112474-70-1 <(4-chlorophenylthio)methyl>trimethylsilane 
• 106-54-7 p-Chlorothiophenol 

Downstream Products

• 5380-97-2 2<(4-chlorophenylthio)methyl>furan 
• 112474-66-5 <1-(4-chlorophenylthio)oct-3-enyl>trimethylsilane 
• 103559-15-5 <4-chlorophenylthio(3,4-methylenedioxyphenyl)methyl>trimethylsilane 
• 112474-62-1 <4-chlorophenylthio(4-phenoxyphenyl)methyl>trimethylsilane 
• 112474-71-2 4,4'-oxybistrimethylsilane 
• 103559-13-3 <4-chlorophenylthio(3,4-dimethoxyphenyl)methyl>trimethylsilane 
• 112474-80-3 trimethylsilane 
• 112474-63-2 [(4-Chloro-phenylsulfanyl)-naphthalen-2-yl-methyl]-trimethyl-silane 
• 129084-92-0 5-[(4-Chloro-phenylsulfanyl)-trimethylsilanyl-methyl]-6,6-dimethyl-tetrahydro-pyran-2-one 
• 112474-69-8 methyl 12-(4-chlorophenylthio)-12-trimethylsilyldodec-9-enoate 
• 103559-10-0 <4-chlorophenylthio(4-methylphenyl)methyl>trimethylsilane 
• 103559-16-6 <4-chlorophenylthio(2,4-dimethoxyphenyl)methyl>trimethylsilane 
• 112474-78-9 <1-(4-chlorophenylsulphonyl)undec-3-enyl>trimethylsilane 
• 112489-73-3 <1-(4-chlorophenylthio)nona-1,3-dienyl>trimethylsilane 

Relevant articles and documents

Reaction of trimethylsilanes with Arenes and Alk-1-enes in the Presence of Lewis Acid: Syntheses of - and (1-Arylthioalk-3-enyl)-trimethylsilanes

Treatment of equimolar amounts of the trimethylsilanes (2) or (3) and electron-rich arenes with an equimolar amount of Lewis acid (SnCl4 or TiCl4) gave the Friedel-Crafts reaction products, trimethylsilanes (4) or (5), in high yields.Similar treatment of the chlorides (2) or (3) with alk-1-enes gave ene type products, trimethylsilanes (12) or (13), in moderate yields.Some chemical transformations of these products are also described.

INTRODUCTION OF AN ARYLTHIO(TRIMETHYLSILYL)METHYL GROUP INTO ARENES BY FRIEDEL-CRAFTS REACTION: SYNTHESIS OF ARYLMETHYLTRIMETHYLSILANES

Friedel-Crafts reactions of trimethylsilanes (1a, b) with arenes gave trimethylsilanes (2a,b), which were converted into arylmethyltrimethylsilanes (3) by reduction with Raney nickel.