104539-21-1

Basic information

• Product Name: Ethane, 1-(2-iodoethoxy)-2-methoxy-
• CAS NO: 104539-21-1
• Molecular Formula: C5H11IO2
• Molecular Weight: 230.046
• Mol File: 104539-21-1.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Ethane, 1-(2-iodoethoxy)-2-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethane, 1-(2-iodoethoxy)-2-methoxy-(104539-21-1)
• EPA Substance Registry System: Ethane, 1-(2-iodoethoxy)-2-methoxy-(104539-21-1)

Safety Data

• Hazardous Substances Data: 104539-21-1(Hazardous Substances Data)

Upstream product

• 111-90-0 ethoxyethoxyethanol 
• 50586-80-6 toluene-4-sulfonic acid 2-(2-methoxyethoxy)ethyl ester 
• 111-77-3 2-(2-methoxyethoxy)ethyl alcohol 

Downstream Products

• 1391034-56-2 N-butyl-N-[2-(2-methoxyethoxy)ethyl]aziridinium bis(trifluoromethanesulfonyl)imide 
• 1391034-52-8 N-butyl-N-[2-(2-methoxyethoxy)ethyl]aziridinium iodide 
• 1421622-10-7 (E)-7-(2-(7-(bis(4-(2-(2-methoxyethoxy)ethoxy)phenyl)-amino)-9,9-bis(2-(2-methoxyethoxy)ethyl)-9H-fluoren-2-yl)vinyl)-9,9-bis(2-(2-methoxyethoxy)ethyl)-9H-fluorene-2-carbaldehyde 
• 1421622-11-8 N,N-bis(4-(2-(2-methoxyethoxy)ethoxy)phenyl)-9,9-bis(2-(2-methoxyethoxy)ethyl)-7-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-fluoren-2-amine 
• 1421622-12-9 7-(7-(bis(4-(2-(2-methoxyethoxy)ethoxy)phenyl)amino)-9,9-bis(2-(2-methoxy-ethoxy)ethyl)-9H-fluoren-2-yl)-2,3-dihydrothieno[3,4-b][1,4]dioxine-5-carbaldehyde 
• 1421622-15-2 (E)-3-(7-(7-(bis(4-(2-(2-methoxyethoxy)ethoxy)phenyl)-amino)-9,9-bis(2-(2-methoxyethoxy)ethyl)-9H-fluoren-2-yl)-2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)-2-cyanoacrylic acid 
• 1421622-08-3 7-bromo-N,N-bis(4-(2-(2-methoxyethoxy)ethoxy)phenyl)-9,9-bis(2-(2-methoxy-ethoxy)ethyl)-9H-fluorene-2-amine 
• 1619229-60-5 C₁₆H₂₉NO₂Si 
• 1443384-43-7 C₂₁H₂₃NO₄S₇ 
• 64994-51-0 4-[2-(2-methoxyethoxy)ethoxy]benzaldehyde 
• 1421071-28-4 C₃₉H₃₅BClF₂N₄O₆Re 
• 1421071-26-2 C₃₆H₃₅BF₂N₄O₃ 
• 1421071-25-1 C₂₄H₂₈BF₂IN₂O₃ 
• 1421071-24-0 C₂₄H₂₉BF₂N₂O₃ 

Relevant articles and documents

Synthesis of pyrrolidinium-based poly(ionic liquid) electrolytes with poly(ethylene glycol) side chains

The synthesis and characterization of a new family of pyrrolidinium based poly(ionic liquid) (PIL) electrolytes with poly(ethylene glycol) (PEG) pendant groups is reported. The PILs were synthesized from a diallyl methyl amine hydrochloride monomer, which

Aqueous supramolecular polymer formed from an amphiphilic perylene derivative

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Visible light-absorbing rhenium(i) tricarbonyl complexes as triplet photosensitizers in photooxidation and triplet-triplet annihilation upconversion

We prepared N^N Re(i) tricarbonyl chloride complexes (Re-1 and Re-2) that give very strong absorption of visible light. To this end, it is for the first time that boron dipyrimethane (Bodipy) was used to prepare Re(i) tricarbonyl chloride complexes. The π-conjugation linker between the π-conjugation framework of the antenna Bodipy and the Re(i) coordination centre ensures efficient intersystem crossing (ISC). Re-0 without visible light-harvesting ligand was prepared as a model complex in the photophysical studies. Re-1 (with Bodipy) and Re-2 (with carbazole-ethynyl Bodipy) show unprecedented strong absorption of visible light at 536 nm (ε = 91700 M-1 cm -1) and 574 nm (ε = 64600 M-1 cm-1), respectively. Interestingly, different from Re-0, Re-1 and Re-2 show fluorescence of the ligand, not the phosphorescence of the Re(i) coordination centre. However, long-lived triplet excited states were observed upon visible light excitation (τT = 104.0 μs for Re-1; τT = 127.2 μs for Re-2) vs. the short lifetime of Re-0 (τT = 26 ns). With nanosecond time-resolved transient absorption spectroscopy and DFT calculations, we proved that the triplet excited states of Re-1 and Re-2 are localized on the Bodipy ligands. The complexes were used as triplet photosensitizers for two triplet-triplet-energy-transfer (TTET) processes, i.e.1O2 mediated photooxidation and triplet-triplet annihilation (TTA) upconversion. With the strong visible light-harvesting ability, Re-1 proved to be a better 1O2 photosensitizer than the conventional triplet photosensitizer tetraphenylporphyrin (TPP). Significant upconversion was observed with Re-1 as the triplet photosensitizer. Our result is useful for preparation of Re(i) tricarbonyl chloride complexes that show strong absorption of visible light and long-lived triplet excited states and for the application of these complexes as triplet photosensitizers in photocatalysis, photodynamic therapy and TTA upconversion. The Royal Society of Chemistry 2013.