10539-50-1

Basic information

• Product Name: Butanedioic acid, benzoyl-, diethyl ester
• CAS NO: 10539-50-1
• Molecular Formula: C15H18O5
• Molecular Weight: 278.305
• Mol File: 10539-50-1.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Butanedioic acid, benzoyl-, diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Butanedioic acid, benzoyl-, diethyl ester(10539-50-1)
• EPA Substance Registry System: Butanedioic acid, benzoyl-, diethyl ester(10539-50-1)

Safety Data

• Hazardous Substances Data: 10539-50-1(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 141-05-9 Diethyl maleate 
• 64-17-5 ethanol 
• 29392-77-6 sodium 3-ethoxy-3-oxo-1-phenylprop-1-en-1-olate 
• 105-39-5 chloroacetic acid ethyl ester 
• 94-02-0 ethyl 3-oxo-3-phenylpropionate 
• 105-36-2 ethyl bromoacetate 
• 827-36-1 2-(N,N-dimethylamino)-2-phenylacetonitrile 
• 623-91-6 diethyl Fumarate 
• 611-73-4 Benzoylformic acid 
• 1520-50-9 but-2-enedioic acid diethyl ester 
• 1075240-62-8 C₂₃H₃₄O₅Si 
• 38109-73-8 ethyl 4-trimethylsiloxy-4-phenylpropenoate 
• 92975-30-9 diethyl 3-phenyl-3-trimethylsiloxy-1,2-cyclopropanedicarboxylate 

Downstream Products

• 132664-63-2 1-(4-methoxy-phenyl)-4-(4-methoxy-phenylhydrazono)-5-oxo-4,5-dihydro-1H-pyrazole-3-carboxylic acid ethyl ester 
• 2051-95-8 succinylbenzene 
• 952016-81-8 (7-hydroxy-2-oxo-4-phenyl-2H-chromen-3-yl)-acetic acid ethyl ester 
• 7104-71-4 5-oxo-1-o-tolyl-4-((Z)-o-tolylhydrazono)-4,5-dihydro-1H-pyrazole-3-carboxylic acid ethyl ester 
• 123-56-8 Succinimide 
• 64-17-5 ethanol 
• 124-38-9 carbon dioxide 
• 4767-01-5 2-methyl-3-oxo-3-phenylpropionic acid 
• 1026290-56-1 2-(benzo[1,3]dioxol-5-yl-hydroxy-methyl)-3-benzoyl-succinic acid diethyl ester 
• 53684-30-3 ethyl trans-5-oxo-2-phenyl-tetrahydrofuran-3-carboxylate 
• 53684-30-3 ethyl cis-5-oxo-2-phenyl-tetrahydrofuran-3-carboxylate 

Relevant articles and documents

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Intermolecular Interactions and Energetics in the Crystalline π-π Stacks and Associated Model Dimer Systems of Asymmetric Halogenated Diketopyrrolopyrroles

Four novel structurally analogous asymmetric, halogenated N-benzyl substituted diketopyrrolopyrroles (DPP) have been synthesized, and their crystal structures obtained. All four crystal structures exhibit π-π stacks with very small displacements along the

Decarboxylative 1,4-Addition of α-Oxocarboxylic Acids with Michael Acceptors Enabled by Photoredox Catalysis

Enabled by iridium photoredox catalysis, 2-oxo-2-(hetero)arylacetic acids were decarboxylatively added to various Michael acceptors including α,β-unsaturated ester, ketone, amide, aldehyde, nitrile, and sulfone at room temperature. The reaction presents a new type of acyl Michael addition using stable and easily accessible carboxylic acid to formally generate acyl anion through photoredox-catalyzed radical decarboxylation.

Chemoenzymatic and yeast-catalysed synthesis of diastereomeric ethyl γ-phenyl and γ-(n-pyridyl)paraconates

The synthesis of γ-phenyl and γ-(n-pyridyl)paraconates was accomplished by chemical reduction of their respective ketodiester precursors followed by cyclisation of the resulting hydroxy diester intermediates. The cis- and trans-lactones thus obtained were separated and separately subjected to enzymatic hydrolysis with HLAP. The cis-lactonic esters had enantiomeric excesses ranging from 94% to 99%, while for the trans-isomers the ee's ranged from 80% to 93%. The same ketodiester precursors were subjected to reduction with a series of yeasts. The absolute configuration of trans-(-)-2-pyridyl paraconic acid was assigned by means of X-ray analysis of its hydrobromide salt, while the absolute configurations of the other lactones were determined via analysis of their respective CD curves.