108799-99-1

Basic information

• Product Name: phenyl p-toluenesulfinate
• Synonyms: phenyl p-toluenesulfinate
• CAS NO: 108799-99-1
• Molecular Weight: 232.303
• Mol File: 108799-99-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: phenyl p-toluenesulfinate(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl p-toluenesulfinate(108799-99-1)
• EPA Substance Registry System: phenyl p-toluenesulfinate(108799-99-1)

Safety Data

• Hazardous Substances Data: 108799-99-1(Hazardous Substances Data)

Upstream product

• 536-57-2 p-toluene sulfinic acid 
• 3049-07-8 pentaphenylbismuth 
• 19350-72-2 N'-(4-methoxybenzylidene)-4-methylbenzenesulfonohydrazide 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 108-95-2 phenol 

Relevant articles and documents

Synthesis of 3-substituted indazoles from arynes and N-tosylhydrazones

Readily available, stable, and inexpensive N-tosylhydrazones react with arynes under mild reaction conditions to afford 3-substituted indazoles in moderate to good yields. The reaction appears to involve a dipolar cycloaddition of in situ generated diazo

Pentavalent Organobismuth Reagents. Part 3. Phenylation of Enols and of Enolate and other Anions

The phenylation of enols and of enolate anions of ketones, β-diketones and keto esters has been studied using a range of Bi reagents.Under basic conditions C-phenylation is observed and, even hindered, perphenylated compounds are easily synthesized.Under neutral and acidic conditions ordinary ketones do not react and enolic systems give O-phenylation.A number of other anions have been phenylated under basic conditions, including the key compound indole wich mainly gave 3-C-phenylation.All these reactions can be supposed to have one of two alternative mechanisms, which parallel the two mechanisms proposed for the phenylation of phenols.