110177-67-8

Basic information

• Product Name: S-ethyl O-benzyl carbonothioate
• Synonyms: S-ethyl O-benzyl carbonothioate
• CAS NO: 110177-67-8
• Molecular Weight: 196.27
• Mol File: 110177-67-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: S-ethyl O-benzyl carbonothioate(CAS DataBase Reference)
• NIST Chemistry Reference: S-ethyl O-benzyl carbonothioate(110177-67-8)
• EPA Substance Registry System: S-ethyl O-benzyl carbonothioate(110177-67-8)

Safety Data

• Hazardous Substances Data: 110177-67-8(Hazardous Substances Data)

Upstream product

• 463-58-1 carbon oxide sulfide 
• 75-03-6 ethyl iodide 
• 100-51-6 benzyl alcohol 
• 125178-42-9 Thiocarbonic acid O-benzyl ester 

Downstream Products

• 501-53-1 benzyl chloroformate 

Relevant articles and documents

Benzyl chloroformate (CbzCl) synthesis using carbon monoxide as a carbonyl source

A novel non-phosgene synthetic method for benzyl chloroformate (CbzCl) was established. S-Methyl O-benzyl carbonothioates were prepared by the carbonylation of benzyl alcohols with carbon monoxide and sulfur (or carbonyl sulfide) in the presence of DBU (1,8-diazabicyclo[5.4.0]undec-7-ene) followed by esterification using methyl iodide in good yields. Then, CbzCl derivatives were successfully synthesized by the chlorination of S-methyl O-benzyl carbonothioates using sulfuryl chloride in excellent yields.