111865-50-0

Basic information

• Product Name: benzyl[1-(4-methylphenyl)but-3-enyl]amine
• Synonyms: benzyl[1-(4-methylphenyl)but-3-enyl]amine
• CAS NO: 111865-50-0
• Molecular Weight: 251.371
• Mol File: 111865-50-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: benzyl[1-(4-methylphenyl)but-3-enyl]amine(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl[1-(4-methylphenyl)but-3-enyl]amine(111865-50-0)
• EPA Substance Registry System: benzyl[1-(4-methylphenyl)but-3-enyl]amine(111865-50-0)

Safety Data

• Hazardous Substances Data: 111865-50-0(Hazardous Substances Data)

Upstream product

• 24850-33-7 allyltributylstanane 
• 104-87-0 4-methyl-benzaldehyde 
• 100-46-9 benzylamine 
• 24431-15-0 (E)-N-benzyl-1-(p-tolyl)methanimine 
• 106-95-6 allyl bromide 

Downstream Products

• 4727-72-4 1-benzyl-4-hydroxypiperidine 

Relevant articles and documents

Efficient synthesis of homoallylic alcohols/amines from allyltributylstannane and carbonyl compounds/imines using iodine as catalyst under acetic acid-water medium

This paper describes a general method for the synthesis of homoallylic alcohols and amines by nucleophilic addition reaction of allyltributylstannane to carbonyl compounds and aldimines where iodine acts as a catalyst in H2O/acetic acid (1:1) medium. Only 10 mol% of I2 is required for various organic transformations. By using this process, various homoallylic alcohols and amines are produced in good to excellent yields.

ELECTROREDUCTIVE "BARBIER TYPE" ALLYLATION OF IMINES WITH A COMBINATION OF A Pb(O)/Pb(II) REDOX MEDIATOR AND SACRIFICAL ANODE (Al)

An electroreductive "Barbier Type" allylation of imines with allyl bromide has been performed in a PbBr2/Bu4NBr/THF-(Al anode)-(Pt cathode) system.A combination of Pb(O)/Pb(II) redox and a sacrifical aluminum anode works as a madiator for both cathodic an