113893-60-0

Basic information

• Product Name: 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl diphenylphosphinate
• CAS NO: 113893-60-0
• Molecular Weight: 740.833
• Mol File: 113893-60-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl diphenylphosphinate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl diphenylphosphinate(113893-60-0)
• EPA Substance Registry System: 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl diphenylphosphinate(113893-60-0)

Safety Data

• Hazardous Substances Data: 113893-60-0(Hazardous Substances Data)

Upstream product

• 1707-03-5 diphenyl-phosphinic acid 
• 74808-09-6 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 1499-21-4 Diphenylphosphinic chloride 

Relevant articles and documents

Stereoselective O-glycosylation reactions using glycosyl donors with diphenylphosphinate and propane-1,3-diyl phosphate leaving groups

Glycosyl donors having a diphenylphosphinate and a propane-1,3-diyl phosphate leaving group were easily prepared by the addition of the anomeric hydroxyl group of 2,3,4,6-tetra-O-benzyl-α,β-D-glucopyranose to diphenylphosphinic and propane-1,3- diyldioxyphosphoryl chlorides. These glycosyl donors were selectively glycosylated with a number of primary and secondary oxygen nucleophiles in the presence of trimethylsilyl triflate (TMSOTf). The use of 1,3-diyl phosphate resulted in the stereoselective formation of β-O-linked glycosides.

Glycosyl Imidates, 37. - Direct O-Glycosylation of Compounds Containing a PO(OH) Moiety

The O-benzylated α- and β-glucosyl trichloroacetimidates 1a-α and 1a-β afforded with the phosphinic acid derivative 2 and the phosphonic acid derivative 3 directly the corresponding O-glucosylated products 4 and 5, resp., with inversion at the anomeric ce