114208-54-7Relevant articles and documents
On the Existence of Discrete TeCl5(-) Ions
Schoenherr, Thomas
, p. 159 - 164 (2007/10/02)
Discrete mononuclear TeCl5(-) anions were prepared for the first time in solid phase in association with bulky cations as tetrabutylammonium and tetraphenylphosphonium.The vibrational spectra imply tetragonal symmetry as for the isoelectronic TeF5(-) anion which is caused by a stereochemically active lone pair.A complete vibrational assignment is given and supported by a normal coordinate treatment for both ions.The significance of the resulting force constants is briefly discussed. - Keywords: Pentahalogenotellurates, Vibrational Spectra, Normal Coordinate Analysis