116905-62-5

Basic information

• Product Name: cis-N-tosyl-2-methyl-3-n-propylaziridine
• CAS NO: 116905-62-5
• Molecular Weight: 253.365
• Mol File: 116905-62-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: cis-N-tosyl-2-methyl-3-n-propylaziridine(CAS DataBase Reference)
• NIST Chemistry Reference: cis-N-tosyl-2-methyl-3-n-propylaziridine(116905-62-5)
• EPA Substance Registry System: cis-N-tosyl-2-methyl-3-n-propylaziridine(116905-62-5)

Safety Data

• Hazardous Substances Data: 116905-62-5(Hazardous Substances Data)

Upstream product

• 7688-21-3 cis-2-hexene 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 4050-45-7 trans-2-hexene 
• 1058-14-6 N-p-tolylsulfonylphosphine imide 
• 70-55-3 toluene-4-sulfonamide 
• 473-34-7 N,N-dichloro-p-toluenesulfonamide 

Relevant articles and documents

Nanocrystalline zinc peroxide mediated unprecedented nitrene transfer: An expeditious access to N-tosylaziridines

An unprecedented zinc peroxide (ZnO2) assisted synthetic strategy is reported for the synthesis of N-tosylaziridines from alkenes by using N-tosyliminotriphenylphosphorane (Ph3PNTs) as a nitrene transfer reagent under mild reaction conditions. The reaction of zinc peroxide with Ph3PNTs yielded a zinc oxaziridine intermediate which subsequently reacts with alkenes to give corresponding N-tosylaziridines in high to excellent yields. The Royal Society of Chemistry 2013.

ALLYLIC AMINATION OF ALKENES BY TOSYLIMINOIODOBENZENE : MANGANESE PORPHYRINS AS SUITABLE CATALYSTS

Manganese-porphyrins and particularly Mn(TPP)(ClO4) were found to be much better catalysts than iron-porphyrins for allylic N-tosylamination of alkenes by tosyliminoiodobenzene.With the former catalyst, cyclohexene was selectively transformed into 3-tosyl