1181454-77-2Relevant articles and documents
Synthesis of 1,2-amino alcohols by decarboxylative coupling of amino acid derived α-amino radicals to carbonyl compounds: Via visible-light photocatalyst in water
Pan, Shulei,Jiang, Min,Hu, Jinjin,Xu, Ruigang,Zeng, Xiaofei,Zhong, Guofu
supporting information, p. 336 - 341 (2020/02/13)
A general and efficient visible-light photoredox-catalysed decarboxylative radical coupling reaction of N-aryl amino acids with aldehydes or ketones for the synthesis of various 1,2-amino alcohols by using water as the solvent at room temperature is described. This protocol is characterised by broad substrate scopes, mild reaction conditions and amenability to gram-scale synthesis, which opens up a simple, mild but effective method to produce 1,2-amino alcohols from readily available starting materials.
Thiourea catalyzed aminolysis of epoxides under solvent free conditions. Electronic control of regioselective ring opening
Chimni, Swapandeep Singh,Bala, Neeraj,Dixit, Vaibhav A.,Bharatam, Prasad V.
experimental part, p. 3042 - 3049 (2010/06/14)
A reactant economizing process for the regioselective aminolysis of epoxides using equimolar quantities of reactants catalyzed by the double hydrogen bond donor N,N′-bis[3,5-bis(trifluoromethyl)phenyl]thiourea is reported. Regioselectivity of the reaction
