1189340-55-3

Basic information

• Product Name: 4-hydroxy-4-(4-tert-butylcarbonyloxymethylphenyl)-2,5-cyclohexadienone
• Synonyms: 4-hydroxy-4-(4-tert-butylcarbonyloxymethylphenyl)-2,5-cyclohexadienone
• CAS NO: 1189340-55-3
• Molecular Weight: 300.354
• Mol File: 1189340-55-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-hydroxy-4-(4-tert-butylcarbonyloxymethylphenyl)-2,5-cyclohexadienone(CAS DataBase Reference)
• NIST Chemistry Reference: 4-hydroxy-4-(4-tert-butylcarbonyloxymethylphenyl)-2,5-cyclohexadienone(1189340-55-3)
• EPA Substance Registry System: 4-hydroxy-4-(4-tert-butylcarbonyloxymethylphenyl)-2,5-cyclohexadienone(1189340-55-3)

Safety Data

• Hazardous Substances Data: 1189340-55-3(Hazardous Substances Data)

Upstream product

• 1189340-62-2 4-(4-hydroxyphenyl)benzyl 2,2-dimethylpropanoate 

Relevant articles and documents

Hypervalent iodine oxidation of phenol derivatives using a catalytic amount of 4-iodophenoxyacetic acid and Oxone as a co-oxidant

Reaction of p-substituted phenols 2 with a catalytic amount of 4-iodophenoxyacetic acid (1) and Oxone as a co-oxidant in tetrahydrofuran (THF) or 1,4-dioxane-water gave the corresponding p-quinols 3 in excellent yields. Reaction of p-dialkoxyarenes 4 in 2,2,2-trifluoroethanol- water gave the corresponding p-quinones 5 in excellent yield without purification. These reactions provide efficient and practical methods for the preparation of p-quinols and p-quinones from p-substituted phenols and p-dialkoxyarenes, respectively. This quinone synthesis was applied to synthesis of blattellaquinone (13), the sex pheromone of the German cockroach Blattella germanica.