1191300-32-9Relevant articles and documents
Copper-catalyzed oxidative alkenylation of C(sp3)-H bonds via benzyl or alkyl radical addition to β-nitrostyrenes
Guo, Shengrong,Yuan, Yanqin,Xiang, Jiannan
supporting information, p. 3093 - 3097 (2015/04/14)
A new method for the preparation of (E)-β-alkylstyrene derivatives has been developed via the addition of a benzyl or alkyl radical to β-nitrostyrenes using di-tert-butyl peroxide (DTBP) as the oxidant in the presence of Cu powder catalyst. The C-H bonds in various toluene derivatives, ethers, alkanes and alcohols were successfully converted into C-C bonds to yield the corresponding (E)-β-alkylstyrene derivatives in moderate to good yields.
Palladium-catalyzed cross-couplings of allylic carbonates with triarylbismuths as multi-coupling atom-efficient organometallic nucleophiles
Rao, Maddali L.N.,Banerjee, Debasis,Giri, Somnath
experimental part, p. 1518 - 1525 (2010/08/03)
Allylic carbonates were efficiently cross-coupled with triarylbismuths under palladium catalysis. Using the optimized protocol, arylations of various allylic carbonates were carried out with triarylbismuths to afford high yields of 1,3-disubstituted prope