119951-72-3

Basic information

• Product Name: Benzoic acid (1R,4S,5R,6R)-4,6-diacetoxy-5-benzyloxy-2-nitro-cyclohex-2-enylmethyl ester
• CAS NO: 119951-72-3
• Molecular Weight: 483.475
• Mol File: 119951-72-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid (1R,4S,5R,6R)-4,6-diacetoxy-5-benzyloxy-2-nitro-cyclohex-2-enylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (1R,4S,5R,6R)-4,6-diacetoxy-5-benzyloxy-2-nitro-cyclohex-2-enylmethyl ester(119951-72-3)
• EPA Substance Registry System: Benzoic acid (1R,4S,5R,6R)-4,6-diacetoxy-5-benzyloxy-2-nitro-cyclohex-2-enylmethyl ester(119951-72-3)

Safety Data

• Hazardous Substances Data: 119951-72-3(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 

Downstream Products

• 119951-73-4 Benzoic acid (1S,2R,3S,4S,5S)-2,4-diacetoxy-5-acetylamino-3-benzyloxy-6-nitro-cyclohexylmethyl ester 
• 121239-57-4 Benzoic acid (1S,2R,3S,4S,5S,6R)-2,4-diacetoxy-3-benzyloxy-5-cyclohexylamino-6-nitro-cyclohexylmethyl ester 
• 119951-73-4 Benzoic acid (1R,2R,3S,4S,5S)-2,4-diacetoxy-5-acetylamino-3-benzyloxy-6-nitro-cyclohexylmethyl ester 
• 119951-73-4 Benzoic acid (1R,2R,3S,4S,5R,6S)-2,4-diacetoxy-5-acetylamino-3-benzyloxy-6-nitro-cyclohexylmethyl ester 
• 121239-57-4 Benzoic acid (1R,2R,3S,4S,5R,6S)-2,4-diacetoxy-3-benzyloxy-5-cyclohexylamino-6-nitro-cyclohexylmethyl ester 
• 119951-74-5 Benzoic acid (1R,2R,3S,4S,5S)-2,4-diacetoxy-5-acetylamino-3-benzyloxy-cyclohexylmethyl ester 
• 121239-64-3 (1R,2S,3S,4R,6R)-4-(6-Amino-purin-9-yl)-2-benzyloxy-6-hydroxymethyl-cyclohexane-1,3-diol 
• 121239-62-1 (-)-9-pseudo-β-D-glucopyranosyladenine 
• 124492-65-5 N-((1S,2S,3S,4R,5R)-2,3,4-Trihydroxy-5-hydroxymethyl-cyclohexyl)-acetamide 
• 121239-61-0 Benzoic acid (1R,2R,3S,4S,5R)-2,4-diacetoxy-5-(6-benzoylamino-purin-9-yl)-3-benzyloxy-cyclohexylmethyl ester 
• 32780-32-8 validamine 
• 121239-59-6 Benzoic acid (1R,2R,3S,4S,5R,6S)-2,4-diacetoxy-5-(6-benzoylamino-purin-9-yl)-3-benzyloxy-6-nitro-cyclohexylmethyl ester 
• 119951-74-5 Benzoic acid (1S,2R,3S,4S,5S)-2,4-diacetoxy-5-acetylamino-3-benzyloxy-cyclohexylmethyl ester 
• 124492-65-5 N-((1S,2S,3S,4R,5S)-2,3,4-Trihydroxy-5-hydroxymethyl-cyclohexyl)-acetamide 

Relevant articles and documents

SYNTHESES OF VALIDAMINE, EPI-VALIDAMINE, AND VALIENAMINE, THREE OPTICALLY ACTIVE PSEUDO-AMINO-SUGARS, FROM D-GLUCOSE

Using as a key reaction a Michael-type addition reaction to nitro-olefins or a substitution reaction for an acetoxyl residue at the β-position of the nitro group in pseudo-nitro-sugar, three optically active pseudo-amino-sugars: validamine, epi-validamine, and valienamine, were synthesized from D-glucose.KEYWORDS--pseudo-amino-sugar optically active; validamine; epi-validamine; valienamine; pseudo-amino-sugar synthesis; Michael-type addition, pseudo-nitro-sugar