120231-99-4

Basic information

• Product Name: C₁₃H₁₄O₂
• Synonyms: C₁₃H₁₄O₂
• CAS NO: 120231-99-4
• Molecular Weight: 202.253
• Mol File: 120231-99-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₃H₁₄O₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₁₄O₂(120231-99-4)
• EPA Substance Registry System: C₁₃H₁₄O₂(120231-99-4)

Safety Data

• Hazardous Substances Data: 120231-99-4(Hazardous Substances Data)

Upstream product

• 55177-35-0 (E)-4-phenyl-2-butenal 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 

Relevant articles and documents

Sequencing cross-metathesis and non-metathesis reactions to rapidly access building blocks for synthesis

The olefin cross-metathesis reaction has been sequenced with four common organic transformations in a one- or two-pot manner to rapidly access useful building blocks. Those reactions are: (1) phosphorus-based olefination (e.g., Wittig and Horner-Wadsworth-Emmons); (2) hydride reduction; (3) Evans propionate aldol reaction; (4) Brown allyl- and Roush crotyl-boration. The products of these reactions include stereodefined 2,4-dienoates, trans allylic alcohols, syn-propionate aldols, and chiral non-racemic homoallylic alcohols, respectively. Many of these intermediates have been carried further to natural products, demonstrating the utility of the methodology.