124339-98-6Relevant articles and documents
Barkley et al.
, p. 1700,1701 (1975)
Metal-catalyzed stereoselective and protecting-group-free synthesis of 1,2-cis-glycosides using 4,6-dimethoxy-1,3,5-triazin-2-yl glycosides as glycosyl donors
Tanaka, Tomonari,Kikuta, Naoya,Kimura, Yoshiharu,Shoda, Shin-Ichiro
supporting information, p. 846 - 848 (2015/06/22)
4,6-Dimethoxy-1,3,5-triazin-2-yl glycosides, glycosyl donors prepared in one step from free saccharides without protection of the hydroxy groups, were stereoselectively and equivalently converted to the corresponding 1,2-cis-glycosides by using a catalytic amount of metal catalyst. This reaction was successfully applied not only to monosaccharides, but also to di- and oligosaccharides.
Protection-free synthesis of alkyl glycosides under hydrogenolytic conditions
Ishihara, Masaki,Takagi, Yuka,Li, Gefei,Noguchi, Masato,Shoda, Shin-Ichiro
supporting information, p. 1235 - 1237 (2013/10/22)
A convenient protection-free synthetic route for the preparation of alkyl glycosides has been developed. The alcoholysis of one-step preparable glycosyl donors, 4,6-dibenzyloxy-1,3,5-triazin-2-yl (DBT) glycosides, under hydrogenolytic conditions gave the corresponding glycosides in good yields without the addition of any acid promoters. The method could be successfully applied to the glycosylation of an acidlabile oligosaccharide.
