1262552-77-1

Basic information

• Product Name: C₃₄H₄₁NO₄
• Synonyms: C₃₄H₄₁NO₄
• CAS NO: 1262552-77-1
• Molecular Weight: 527.704
• Mol File: 1262552-77-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₄H₄₁NO₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₄H₄₁NO₄(1262552-77-1)
• EPA Substance Registry System: C₃₄H₄₁NO₄(1262552-77-1)

Safety Data

• Hazardous Substances Data: 1262552-77-1(Hazardous Substances Data)

Upstream product

• 28339-04-0 4,8-dimethyldecanoic acid 
• 244755-79-1 (1'R,2'R)-trans-2'-(2,3-anthracenedicarboximido)cyclohexanol 

Relevant articles and documents

Pheromone synthesis. Part 245: Synthesis and chromatographic analysis of the four stereoisomers of 4,8-dimethyldecanal, the male aggregation pheromone of the red flour beetle, Tribolium castaneum

All four stereoisomers of 4,8-dimethyldecanal (1) were synthesized from the enantiomers of 2-methyl-1-butanol and citronellal. Enantioselective GC analysis enabled separation of (4R,8R)-1 and (4R,8S)-1 from a mixture of (4S,8R)-1 and (4S,8S)-1, when octakis-(2,3-di-O-methoxymethyl-6-O-tert-butyldimethylsilyl)- γ-cyclodextrin was employed as a chiral stationary phase. Complete separation of the four stereoisomers of 1 on reversed-phase HPLC at -54 °C was achieved after oxidation of 1 to the corresponding carboxylic acid 12 followed by its derivatization with (1R,2R)-2-(2,3-anthracenedicarboximido) cyclohexanol, and the natural 1 was found to be a mixture of all the four stereoisomers.