127154-65-8

Basic information

• Product Name: erythro-1,2-dibromo-1-phenylpropane
• Synonyms: erythro-1,2-dibromo-1-phenylpropane
• CAS NO: 127154-65-8
• Molecular Weight: 277.986
• Mol File: 127154-65-8.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: erythro-1,2-dibromo-1-phenylpropane(CAS DataBase Reference)
• NIST Chemistry Reference: erythro-1,2-dibromo-1-phenylpropane(127154-65-8)
• EPA Substance Registry System: erythro-1,2-dibromo-1-phenylpropane(127154-65-8)

Safety Data

• Hazardous Substances Data: 127154-65-8(Hazardous Substances Data)

Upstream product

• 766-90-5 cis-1-phenyl-1-propylene 
• 873-66-5 1-propenylbenzene 
• 637-50-3 1-phenylpropene 
• 104-54-1 3-Phenylpropenol 
• 1196-45-8 syn-1,2-dibromo-1-phenylpropane 
• 1196-45-8 (1,2-dibromopropyl)benzene 
• 103-65-1 phenylpropane 

Downstream Products

• 673-32-5 1-Phenylprop-1-yne 
• 4962-45-2 rac-(1S,2R)-2-bromo-1-phenyl-1-propan-1-ol 
• 1196-45-8 (1,2-dibromopropyl)benzene 
• 31076-47-8 [(1E)-1-bromoprop-1-en-1-yl]benzene 
• 1196-45-8 syn-1,2-dibromo-1-phenylpropane 
• 31026-78-5 cis-1-bromo-2-methyl-1-phenylethene 
• 88196-06-9 syn-1-phenylpropane-1,2-diol 
• 873-66-5 1-propenylbenzene 
• 200395-89-7 dibromo di-n-hexyl tellurium(IV) 

Relevant articles and documents

BROMOCHLORINATION OF ALKENES WITH DICHLOROBROMATE(1 minus ) ION. II. REGIO- AND STEREOCHEMISTRY FOR THE BROMOCHLORINATION OF 1-PHENYLPROPENES WITH DICHLOROBROMATE(1 minus ) ION.

The bromochlorinations of 1-phenylpropenes with tetrabutylammonium dichlorobromate(1 minus ) in aprotic solvents (dielectric constants 5-36) were found to be completely anti stereospecific and nonregiospecific, although Markownikoff adduct was mainly form

A General Method for the Dibromination of Vicinal sp3C-H Bonds Exploiting Weak Solvent-Substrate Noncovalent Interactions

A general procedure of 1,2-dibromination of vicinal sp3 C-H bonds of arylethanes using N-bromosuccinimide as the bromide reagent without an external initiator has been established. The modulation of the strength of the intermolecular noncovalent interactions between the solvent and arylethane ethanes, quantitatively evaluated via quantum chemical calculations, allows us to circumvent the fact that arylethane ethane cannot be dibrominated through traditional methods. The mechanism was explored by both experiments and quantum chemical calculations, revealing a radical chain with HAA process.

A Cascade Suzuki-Miyaura/Diels-Alder Protocol: Exploring the Bifunctional Utility of Vinyl Bpin

Cascade reactions are an important strategy in reaction design, allowing streamlining of chemical synthesis. Here we report a cascade Suzuki-Miyaura/Diels-Alder reaction, employing vinyl Bpin as a bifunctional reagent in two distinct roles: as an organoboron nucleo phile for cross-coupling and as a Diels-Alder dienophile. Merging these two reactions enables a rapid and operationally simple synthesis of functionalized carbocycles in good yield. The effect of the organoboron subtype on Diels-Alder regioselectivity was investigated and postsynthetic modifications were carried out on a model substrate. The potential for a complementary Heck/Diels-Alder process was also assessed.

Photocatalytic Transfer Hydrogenolysis of Allylic Alcohols on Pd/TiO2: A Shortcut to (S)-(+)-Lavandulol

We report herein a regio- and stereoselective photocatalytic hydrogenolysis of allylic alcohols to form unsaturated hydrocarbons employing a palladium(II)-loaded titanium oxide; the reaction proceeds at room temperature under light irradiation without stoichiometric generation of salt wastes. Olefin and saturated alcohol moieties tolerated the reaction conditions. Hydrogen atoms were selectively incorporated into less sterically congested carbons of the allylic functionalities. This protocol allowed a short-step synthesis of (S)-(+)-lavandulol from (R)-(?)-carvone by avoiding otherwise necessary protection/deprotection steps.