129170-74-7

Basic information

• Product Name: (3R,4R)-4-methyl-1-phenylhex-5-en-3-ol?
• Synonyms: (3R,4R)-4-methyl-1-phenylhex-5-en-3-ol?
• CAS NO: 129170-74-7
• Molecular Weight: 190.285
• Mol File: 129170-74-7.mol
• Article Data: 46

Chemical Properties

• CAS DataBase Reference: (3R,4R)-4-methyl-1-phenylhex-5-en-3-ol?(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4R)-4-methyl-1-phenylhex-5-en-3-ol?(129170-74-7)
• EPA Substance Registry System: (3R,4R)-4-methyl-1-phenylhex-5-en-3-ol?(129170-74-7)

Safety Data

• Hazardous Substances Data: 129170-74-7(Hazardous Substances Data)

Upstream product

• 104-53-0 3-phenyl-propionaldehyde 
• 4784-77-4 (E)-1-Bromo-2-butene 
• 702-04-5 crotyl phenyl sulfide 
• 701-75-7 3-(phenylthio)but-1-ene 
• 18147-55-2 (E)-crotyltrichlorosilane 
• 29310-15-4 (E/Z)-Crotyldimethylchlorosilane 
• 73537-46-9 (Z)-2-Butenylchlorodimethylsilane 
• 35998-93-7 tri-n-butylcrotyltin 
• 66534-32-5 α,α-diisopropyl-β-methylhomoallylic alcohol 
• 444808-75-7 20-((1'R)-hydroxy-(3'E)-penten-1'-yl)-3-oxopregn-4-ene 
• 804559-38-4 (R,R)-crotylsilane 
• 804559-39-5 (R,R)-trans EZ-CrotylMix 
• 69611-01-4 (Z)-2-(but-2-enyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 69611-02-5 (E)-2-(but-2-enyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Downstream Products

• 1419029-03-0 (4R,5R)-5-hydroxy-4-methyl-7-phenylhept-2-en-1-yl (4-methoxyphenyl)carbonate 
• 1419027-22-7 (3R,4S,5S)-5-(4-methoxyphenoxy)-4-methyl-1-phenylhept-6-en-3-ol 
• 1419027-25-0 (3R,4S,5R)-5-(4-methoxyphenoxy)-4-methyl-1-phenylhept-6-en-3-ol 
• 1615707-73-7 (3R,4S)-4-methyl-1-phenylhex-5-en-3-yl acetate 
• 1615707-40-8 C₂₅H₄₂B₂O₅ 
• 1615707-70-4 C₂₀H₂₂O₂ 
• 1615707-42-0 (3R,4S,5S)-4-methyl-1-phenyl-5,6-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)hexan-3-yl acetate 
• 1615707-76-0 tert-butyldiphenyl(((4R,5R,6R)-2,2,5-trimethyl-6-phenethyl-1,3-dioxan-4-yl)methoxy)silane 
• 1615707-75-9 C₃₁H₄₀O₄Si 
• 1615707-74-8 C₁₅H₂₂O₄ 
• 1615707-38-4 (2R,3S,4R)-3-methyl-6-phenylhexane-1,2,4-triol 
• 1615707-71-5 C₂₉H₃₈O₃Si 
• 1615707-72-6 tert-butyldiphenyl(((4R,5S,6R)-2,2,5-trimethyl-6-phenethyl-1,3-dioxan-4-yl)methoxy)silane 

Relevant articles and documents

Cp2TiCl2-Catalyzed Photoredox Allylation of Aldehydes with Visible Light

A Barbier-type Cp2TiCl2-mediated (10 mol %) photoredox allylation of aldehydes under irradiation with visible light (blue light-emitting diodes (LEDs), 450 nm) and in the presence of an organic dye (3DPAFIPN, 5 mol %) with allylbromides is described.

Syn -Selective crotylation of aldehydes using bismuth-crotyl bromide-(1-butyl-3-methylimidazolium bromide) combination: Some synthetic applications

The Bi-[bmim][Br] combination has been found to offer high syn-selectivity in the crotylation of aldehydes with crotyl bromide using practically stoichiometric amounts of the reagents. The room temperature ionic liquid (RTIL), [bmim][Br], activated Bi metal in the presence of oxygen to produce crotylbismuthdibromide, which reacted with the aldehydes at room temperature. The major anti-syn diastereomeric product obtained from the crotylation of (R)-cyclohexylideneglyceraldehyde was utilized for the synthesis of dictyostatin and cryptophycin segments, and (+)-cis-aerangis lactone, using standard synthetic protocols.

Transition-metal-free reductive coupling of 1, 3-butadienes with aldehydes catalyzed by dibutyliodotin hydride

In this study, the Bu2SnIH-catalyzed direct coupling of 1, 3- dienes with aldehydes was developed. This reaction could be suitable for coupling without the use of transition-metal catalysts. Many types of aldehydes were applied to this reaction. The addition of MeOH promoted the catalytic cycle.