13125-52-5

Basic information

• Product Name: 2-Butenenitrile, 4-oxo-4-phenyl-, (E)-
• CAS NO: 13125-52-5
• Molecular Formula: C10H7NO
• Molecular Weight: 157.172
• Mol File: 13125-52-5.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 2-Butenenitrile, 4-oxo-4-phenyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butenenitrile, 4-oxo-4-phenyl-, (E)-(13125-52-5)
• EPA Substance Registry System: 2-Butenenitrile, 4-oxo-4-phenyl-, (E)-(13125-52-5)

Safety Data

• Hazardous Substances Data: 13125-52-5(Hazardous Substances Data)

Upstream product

• 40920-35-2 Dimethylacetal-benzoylacrylnitril 
• 114142-28-8 (3E)-4-phenyl-3-butenoic hydroxamic acid 
• 143056-88-6 Acetic acid 1-cyano-3-oxo-3-phenyl-propyl ester 
• 79311-09-4 essigsaeure-<(E)-1-cyano-3-phenyl-2-propenyl>ester 
• 7677-24-9 trimethylsilyl cyanide 
• 1131-80-2 (E)-3-(N,N-dimethylamino)-1-phenyl-2-propen-1-one 
• 75-86-5 2-hydroxy-2-methylpropanenitrile 
• 3623-15-2 phenyl propargyl ketone 
• 100-52-7 benzaldehyde 
• 1201-93-0 1-phenyl-3-dimethylaminoprop-2-enone 
• 79265-03-5 Acetic acid (E)-1-cyano-3-phenyl-allyl ester 
• 143056-85-3 Acetic acid 1-cyano-3,3-dimethoxy-3-phenyl-propyl ester 
• 83144-17-6 Acetic acid (E)-3-cyano-1-phenyl-allyl ester 
• 3306-07-8 1-benzoyl-2-chloroethene 

Downstream Products

• 101938-57-2 2-morpholino-4-oxo-4-phenyl-butyronitrile 
• 102543-40-8 (+/-)-trans-12-benzoyl-9,10-dihydro-9,10-ethano-anthracene-11-carbonitrile 
• 15806-71-0 (2Z)-4-oxo-4-phenylbut-2-enenitrile 
• 59838-67-4 7,7-dimethyl-5-oxo-2-phenyl-5,6,7,8-tetrahydroquinoline 
• 92855-45-3 4-Oxo-4-phenyl-2-phenylmercapto-butyronitril 
• 1360110-67-3 (2S,3S,4S)-tert-butyl 3-benzoyl-2-cyano-4-((E)-4-ethoxy-4-oxobut-2-en-1-yl)-3,4-dihydro-1H-carbazole-9(2H)-carboxylate 
• 5343-98-6 4-oxo-4-phenylbutanenitrile 
• 2051-95-8 succinylbenzene 

Relevant articles and documents

Metal-free enaminone C-N bond cyanation for the stereoselective synthesis of (E)- And (Z)-β-cyano enones

A highly practical method for C-CN bond formation by C-N bond cleavage on enaminones leading to the efficient synthesis of β-cyano enones is developed. The reactions take place efficiently to provide (E)-β-cyano enones with only a molecular iodine catalyst. In addition, the additional employment of oxalic acid enables the selective synthesis of (Z)-β-cyano enones.

Tunable Trifunctionalization of Tertiary Enaminones for the Regioselective and Metal-Free Synthesis of Discrete and Proximal Phosphoryl Nitriles

This paper reports an unprecedented trifunctionalization of tertiary enaminones for the synthesis phosphoryl nitriles by the reactions of enaminones with diarylphosphine oxides and trimethylsilyl cyanide (TMSCN) without the use of any metal reagent. Emplo

Metal free electrophilic fluoro-cyclization of unsaturated N-hydroxy- and N-acetoxyamides with N-F reagents

Metal-free electrophilic fluoro-cyclizations of the respective unsaturated N-hydroxy- and N-acetoxy-amides under action of the 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2 2 2]octane bis(tetrafluoroborate) (F-TEDA-BF4; trade name Selectfluor)