1353722-70-9

Basic information

• Product Name: (E)-8-(tosylamino)oct-2-en-1-ol
• Synonyms: (E)-8-(tosylamino)oct-2-en-1-ol
• CAS NO: 1353722-70-9
• Molecular Weight: 297.419
• Mol File: 1353722-70-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-8-(tosylamino)oct-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-8-(tosylamino)oct-2-en-1-ol(1353722-70-9)
• EPA Substance Registry System: (E)-8-(tosylamino)oct-2-en-1-ol(1353722-70-9)

Safety Data

• Hazardous Substances Data: 1353722-70-9(Hazardous Substances Data)

Upstream product

• 110046-51-0 hept-6-en-1-yl 4-methylbenzenesulfonate 
• 70-55-3 toluene-4-sulfonamide 
• 1353723-23-5 ethyl (E)-8-(tosylamino)oct-2-enoate 
• 1353723-22-4 6-(toxylamino)hexanal 
• 1353723-21-3 N-(hept-6-en-1-yl)-4-methylbenzenesulfonamide 

Relevant articles and documents

Enantioselective synthesis of pyrrolidine-, Piperidine-, and azepane-type N -heterocycles with α-alkenyl substitution: The CpRu-catalyzed dehydrative intramolecular N -allylation approach

A cationic CpRu complex of chiral picolinic acid derivatives [(R)- or (S)-Cl-Naph-PyCOOCH2CH=CH2] catalyzes asymmetric intramolecular dehydrative N-allylation of N-substituted ω-amino- and -aminocarbonyl allylic alcohols with a substrate/catalyst ratio of up to 2000 to give α-alkenyl pyrrolidine-, piperidine-, and azepane-type N-heterocycles with an enantiomer ratio of up to >99:1. The wide range of applicable N-substitutions, including Boc, Cbz, Ac, Bz, acryloyl, crotonoyl, formyl, and Ts, significantly facilitates further manipulation toward natural product synthesis.