13541-22-5

Basic information

• Product Name: (1,1,1,6,6,6-hexafluorohexane-3,4-diyl)dibenzene
• Synonyms: (1,1,1,6,6,6-hexafluorohexane-3,4-diyl)dibenzene
• CAS NO: 13541-22-5
• Molecular Weight: 346.315
• Mol File: 13541-22-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1,1,1,6,6,6-hexafluorohexane-3,4-diyl)dibenzene(CAS DataBase Reference)
• NIST Chemistry Reference: (1,1,1,6,6,6-hexafluorohexane-3,4-diyl)dibenzene(13541-22-5)
• EPA Substance Registry System: (1,1,1,6,6,6-hexafluorohexane-3,4-diyl)dibenzene(13541-22-5)

Safety Data

• Hazardous Substances Data: 13541-22-5(Hazardous Substances Data)

Upstream product

• 3238-20-8 (1-bromo-3,3,3-trifluoropropyl)benzene 
• 100-42-5 styrene 
• 623-26-7 terephthalonitrile 
• 75-63-8 Bromotrifluoromethane 
• 2926-29-6 Langlois reagent 

Relevant articles and documents

Copper-mediated radical 1,2-bis(trifluoromethylation) of alkenes with sodium trifluoromethanesulfinate

An efficient chemoselective 1,2-bis(trifluoromethylation) of alkenes with CF3SO2Na promoted by t-BuOOH/CuCl was developed. This protocol provided the first convenient preparation of 1,2-bis(trifluoromethylated) compounds by the vicinal difunctionalization of alkenes. The chemoselectivity of this reaction was accomplished by increasing the concentration of the CF3 radical.

UNUSUAL REACTIONS RESULTING FROM THE ADDITION ON OLEFINS OF TRIFLUOROMETHYL RADICALS OBTAINED FROM DISSOCIATIVE ELECTRON TRANSFER BETWEEN ELECTROCHEMICALLY GENERATED AROMATIC ANION RADICALS AND TRIFLUOROMETHYL BROMIDE

Dissociative electron transfer between the anion radical of terephthalonitrile and CF3Br in the presence of olefinic compounds results in the formation of an addition radical which eventually dimerizes into 1,1,1,6,6,6-hexafluoro-3,4-diphenyl hexane, in t