1359950-48-3

Basic information

• Product Name: C₂₃H₂₆OSi
• Synonyms: C₂₃H₂₆OSi
• CAS NO: 1359950-48-3
• Molecular Weight: 346.544
• Mol File: 1359950-48-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₃H₂₆OSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₃H₂₆OSi(1359950-48-3)
• EPA Substance Registry System: C₂₃H₂₆OSi(1359950-48-3)

Safety Data

• Hazardous Substances Data: 1359950-48-3(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 139706-45-9 benzyl tert-butyldiphenylsilyl ether 

Downstream Products

• 1330776-76-5 2-hydroxy-5,5-dimethyl-2-(3-oxo-1,3-diphenylpropyl)cyclohexane-1,3-dione 
• 1359950-53-0 (tert-butyldiphenylsilyl)(phenyl)methanone 
• 1330776-77-6 2-hydroxy-5,5-dimethyl-2-(3-oxo-3-phenyl-1-p-tolylpropyl)cyclohexane-1,3-dione 
• 1330776-78-7 2-hydroxy-2-[1-(4-methoxyphenyl)-3-oxo-3-phenylpropyl]-5,5-dimethylcyclohexane-1,3-dione 
• 1330776-79-8 2-[1-(4-chlorophenyl)-3-oxo-3-phenylpropyl]-2-hydroxy-5,5-dimethylcyclohexane-1,3-dione 
• 1330776-82-3 2-hydroxy-5,5-dimethyl-2-[1-(4-nitrophenyl)-3-oxo-3-phenylpropyl]cyclohexane-1,3-dione 
• 1330776-84-5 2-[1,3-bis(4-chlorophenyl)-3-oxopropyl]-2-hydroxy-5,5-dimethylcyclohexane-1,3-dione 

Relevant articles and documents

Metal-free relay oxidation: Valuable synthesis of acylsilane and ketones under aerobic oxidation

In this letter, an example of interesting metal-free relay air oxidation of -hydroxysilanes, promoted by the hydroperoxidated carbonyl compounds derived from the Michael reaction of 5,5-dimethylcyclohexane-1,3-dione and chalcone, is reported. A series of aromatic acylsilanes with TBDPS were obtained in promising isolated yields. In addition, as an extension of the relay oxidation under aerobic conditions, this catalyst-free relay oxidation induced by diketone can be applied to the oxidation of general aromatic alcohols (up to 75% yield). Georg Thieme Verlag Stuttgart · New York.