137559-30-9

Basic information

• Product Name: methyl N^α-(benzyloxycarbonyl)-L-ornithinate
• Synonyms: methyl N^α-(benzyloxycarbonyl)-L-ornithinate
• CAS NO: 137559-30-9
• Molecular Weight: 280.324
• Mol File: 137559-30-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl N^α-(benzyloxycarbonyl)-L-ornithinate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl N^α-(benzyloxycarbonyl)-L-ornithinate(137559-30-9)
• EPA Substance Registry System: methyl N^α-(benzyloxycarbonyl)-L-ornithinate(137559-30-9)

Safety Data

• Hazardous Substances Data: 137559-30-9(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 2640-58-6 Nα-benzyloxycarbonyl-L-ornithine 

Downstream Products

• 137559-31-0 Nα-Benzyloxycarbonyl-Nδ-(Nα-hexadecanoyl-Nδ-benzyloxycarbonyl-L-ornithyl)-L-ornithinmethylester 
• 145013-07-6 C₂₅H₃₈N₄O₈ 
• 137559-25-2 Nα-Benzyloxycarbonyl-Nδ-hexadecanoyl-L-ornithinmethylester 
• 185825-41-6 2-[((S)-4-Benzyloxycarbonylamino-4-methoxycarbonyl-butylcarbamoyl)-methyl]-benzoic acid 
• 401809-97-0 6-(4-benzyloxycarbonylamino-4-methoxycarbonyl-butylcarbamoyl)-1,3-dihydro-isoindole-2,5-dicarboxylic acid 2-tert-butyl ester 

Relevant articles and documents

Design and synthesis of Fmoc-SPPS-ready iodoarene amino acid pre-catalysts and their reactivity in the catalytic oxytosylation of ketones

A small suite of iodo-aryl amide containing amino acids were synthesized and assessed as catalysts for the hypervalent iodine(III) mediated α-oxytosylation of ketones. The efficiency of each catalyst was determined by comparing the relative rates of catalysis in the direct α-oxytosylation of propiophenone. In addition, these catalysts can be easily converted to congeners that are suitable for Fmoc-solid phase peptide synthesis for facile incorporation into a chiral peptide framework. This work facilitates the broader goal of our program to develop peptide-based enantioselective catalysts for hypervalent iodine chemistry.