1380423-62-0Relevant articles and documents
Gold(I)-catalyzed stereoconvergent, intermolecular enantioselective hydroamination of allenes
Butler, Kristina L.,Tragni, Michele,Widenhoefer, Ross A.
supporting information; experimental part, p. 5175 - 5178 (2012/07/27)
Gold and silver: A 1:2 mixture of [{(S)-1}(AuCl)2] and AgBF 4 catalyzes the enantioselective hydroamination of chiral, racemic 1,3-disubstituted allenes with N-unsubstituted carbamates to form N-allylic carbamates in good yield, with high regio- and diastereoselectivity, and up to 92% ee (see scheme, Cbz=benzyloxycarbonyl). Copyright