141228-89-9Relevant articles and documents
Synthesis of fluorine-containing 1,4-dioxa-2-azaspiro-[4.5]deca-2,6,9- trienes by reaction of polyfluorinated cyclohexa-2,5-dienones with nitrile oxides
Kovtonyuk, V. N.,Kobrina, L. S.,Gatilov, Yu. V.
, p. 783 - 787,5 (2020/08/31)
4-Pentafluorophenoxy-, 4-nitro-, and 4-chloropentafluorocyclohexa-2,5-dien- 1-ones and 3,4,5-tris-(pentafluorophenoxy)trifluorocyclohexa-2,5-dien-1-one react with some benzonitrile and acetonitrile oxides exclusively at the carbonyl group, leading to the formation of mixtures of diastereoisomeric fluorinated 1,4-dioxa-2-azaspiro[4.5]deca-2,6,9-trienes in good yield.
Nucleophilic substitution of a fluorine atom in perfluorophenoxycyclohexadienones. Synthesis of 1,3,5-trisubstituted fluorine-containing polyphenyl ethers
Kovtonyuk, V.N.,Kobrina, L.S.
, p. 2029 - 2036 (2007/10/02)
The reaction of perfluoro-4-phenoxy-2,5-cyclohexadien-1-one with sodium pentafluorophenolate or phenols in the presence of potassium carbonate at 20 deg C gave products of the substitution of fluorine atoms at C3 and C5 in the dienon