14253-59-9

Basic information

• Product Name: (2R,3R)-endo-3-(Methoxycarbonyl)norbornane-exo-2-carboxylic acid
• CAS NO: 14253-59-9
• Molecular Weight: 198.219
• Mol File: 14253-59-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (2R,3R)-endo-3-(Methoxycarbonyl)norbornane-exo-2-carboxylic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R)-endo-3-(Methoxycarbonyl)norbornane-exo-2-carboxylic acid(14253-59-9)
• EPA Substance Registry System: (2R,3R)-endo-3-(Methoxycarbonyl)norbornane-exo-2-carboxylic acid(14253-59-9)

Safety Data

• Hazardous Substances Data: 14253-59-9(Hazardous Substances Data)

Upstream product

• 29745-04-8 norcantharidin 
• 67-56-1 methanol 
• 17812-27-0 cis-5-norbornene-endo-2,3-dicarboxylic anhydride 
• 129-64-6 3,6-endomethylene-1,2,3,6-tetrahydrophthalic anhydride 
• 2746-19-2 (1R,2R,6S,7S)-4-oxa-tricyclo[5.2.1.0^2,6]dec-8-ene-3,5-dione 
• 4098-47-9 Dimethyl norbornane-trans-2,3-dicarboxylate 
• 3014-58-2 dimethyl (exo,endo)-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate 
• 624-49-7 dimethylfumarate 
• 130362-20-8 (1S,2R,3S,4R)-7-Oxa-bicyclo[2.2.1]heptane-2,3-dicarboxylic acid 2-((S)-methoxycarbonyl-phenyl-methyl) ester 3-methyl ester 
• 130362-20-8 (1R,2S,3R,4S)-7-Oxa-bicyclo[2.2.1]heptane-2,3-dicarboxylic acid 2-((R)-methoxycarbonyl-phenyl-methyl) ester 3-methyl ester 
• 14166-28-0 exo-bicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride 
• 135029-24-2 (1S,2R,3S,4S)-2-<(S)-Mandeloxycarbonyl>-7-oxabicyclo<2.2.1>heptane-3-carboxylic Acid 
• 542-92-7 cyclopenta-1,3-diene 
• 123286-70-4 (1S,2S,3S,4R)-endo-3-(methoxycarbonyl)-bicyclo[2.2.1]hept-5-en-exo-2-carboxylic acid 

Relevant articles and documents

Cinchona alkaloid derivative modified Fe3O4nanoparticles for enantioselective ring opening of: Meso -cyclic anhydrides

In the present work, the molecular framework of quinidine was modified at the methoxy functional group of the C6′ carbon of the quinoline moiety with a long-chain carboxylic acid group (-COOH) and it was used as a capping agent during the synthesis of Fe3

Enzymatic optical resolution of norbornanecarboxylic esters using Pig Liver Esterase

The hydrolysis of a series of norbornane-type carboxylic esters catalyzed by pig liver esterase (PLE) has been investigated.It was found that an exo-ester function (syn to the C7 methylene group) is hydrolyzed with high preference.Enantioselective hydrolysis can be accomplished when a vicinal carbonyl-containing function (ester, formyl, acetyl) is present in a trans position with respect to the exo ester.The regiospecifity of the enzymatic hydrolysis has been used for the separation of exo/endo mixtures of the cycloadducts derived from cyclopentadiene and alkene esters.The regiospecifity and enantioselectivity of the enzymatic hydrolysis of norbornane-type esters were analyzed in terms of Tamm's substrate model and also by Griengl's method.

Optical and Neutron Inelastic Scattering Study of 2,3-Dimethylnorbornanes

We have measured the infrared, Raman, and neutron vibrational spectra of the 2,3-dimethylnorbornanes with two CH3 or CD3 groups in the 2- and 3-exo or endo positions.A normal-coordinate analysis has been carried out.No coupling reflecting the strain due to the methyl group appears in the C-CH3 bending and torsional modes of the trans isomer, but appears in the cis-exo isomer (average value 23 cm-1) and in the cis-endo isomer (average value 28 cm-1.The frequencies are used for the determination of the thermodynamic contribution to the standard free energy differences.