14419-73-9

Basic information

• Product Name: methyl 4,6-O-benzylidene-2,3-O-carbonyl-α-D-glucopyranoside
• Synonyms: methyl 4,6-O-benzylidene-2,3-O-carbonyl-α-D-glucopyranoside
• CAS NO: 14419-73-9
• Molecular Weight: 308.288
• Mol File: 14419-73-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 4,6-O-benzylidene-2,3-O-carbonyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4,6-O-benzylidene-2,3-O-carbonyl-α-D-glucopyranoside(14419-73-9)
• EPA Substance Registry System: methyl 4,6-O-benzylidene-2,3-O-carbonyl-α-D-glucopyranoside(14419-73-9)

Safety Data

• Hazardous Substances Data: 14419-73-9(Hazardous Substances Data)

Upstream product

• 79549-74-9 methyl 4,6-O-benzylidene-α-D-allopyranoside 
• 33842-02-3 dichloromethylenedimethyliminium chloride 

Downstream Products

• 3150-15-0 methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside 
• 6752-76-7 methyl 4,6-O-benzylidene-2-O-methyl-α-D-altropyranoside 

Relevant articles and documents

The Reaction of N-Dichloromethylene-N,N-dimethylammonium Chloride (Viehe's Salt) with Some Carbohydrate Diols

The reaction of Viehe's salt (Me2N1+=CCl2Cl1-) with various carbohydrate diols (manno, allo) in the presence of a base is reported, the products being, after hydrolysis, either carbonate (with pyridine) or the carbamate (with triethylamine).A rationalization of the two different types of product formed is given in terms of the stereoelectronic control proposal by Deslongchamps.