1443036-49-4 Usage
Description
Benzoyl(phenyliodonio)(trifluoromethanesulfonyl)methanide, also known as PhI(OCOCF3)(OTf), is a powerful and versatile hypervalent iodine reagent used in organic synthesis. It is characterized by its trifluoromethanesulfonyl group, which enhances the reactivity and stability of the reagent, making it an effective tool in the synthesis of complex organic molecules. PhI(OCOCF3)(OTf) is also known for its mild and selective reactivity, making it a valuable addition to the arsenal of synthetic chemists.
Uses
Used in Organic Synthesis:
Benzoyl(phenyliodonio)(trifluoromethanesulfonyl)methanide is used as a reagent in organic synthesis for its ability to participate in various reactions, including oxidation, rearrangement, and cyclization processes. Its mild and selective reactivity allows for the efficient synthesis of complex organic molecules.
Used in Pharmaceutical Preparation:
PhI(OCOCF3)(OTf) is used as a reagent in the preparation of pharmaceuticals due to its effectiveness in the synthesis of complex organic molecules, which are often found in drug compounds. Its mild and selective reactivity ensures that the desired products are formed with minimal side reactions.
Used in Natural Product Synthesis:
Benzoyl(phenyliodonio)(trifluoromethanesulfonyl)methanide is used as a reagent in the synthesis of natural products, which often require the formation of complex organic molecules. Its versatility and selectivity make it a valuable tool in the preparation of these biologically active compounds.
Used in the Synthesis of Complex Organic Molecules:
PhI(OCOCF3)(OTf) is used as a reagent in the synthesis of complex organic molecules, where its enhanced reactivity and stability, provided by the trifluoromethanesulfonyl group, allow for efficient and selective reactions. This makes it an important tool in the field of organic chemistry for the preparation of intricate molecular structures.
Check Digit Verification of cas no
The CAS Registry Mumber 1443036-49-4 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,4,4,3,0,3 and 6 respectively; the second part has 2 digits, 4 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1443036-49:
(9*1)+(8*4)+(7*4)+(6*3)+(5*0)+(4*3)+(3*6)+(2*4)+(1*9)=134
134 % 10 = 4
So 1443036-49-4 is a valid CAS Registry Number.
1443036-49-4Relevant articles and documents
Trifluoromethanesulfonyl hypervalent iodonium ylide for copper-catalyzed trifluoromethylthiolation of enamines, indoles, and β-keto esters
Yang, Yu-Dong,Azuma, Ayaka,Tokunaga, Etsuko,Yamasaki, Mikio,Shiro, Motoo,Shibata, Norio
supporting information, p. 8782 - 8785 (2013/07/26)
A novel electrophilic-type trifluoromethylthiolation reagent, a trifluoromethanesulfonyl hypervalent iodonium ylide, was designed and reacted well with various nucleophiles to afford the desired CF3S-substituted products. In situ reduction of t
