1445972-51-9

Basic information

• Product Name: C₂₀H₂₃FeN
• Synonyms: C₂₀H₂₃FeN
• CAS NO: 1445972-51-9
• Molecular Weight: 333.256
• Mol File: 1445972-51-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₀H₂₃FeN(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₀H₂₃FeN(1445972-51-9)
• EPA Substance Registry System: C₂₀H₂₃FeN(1445972-51-9)

Safety Data

• Hazardous Substances Data: 1445972-51-9(Hazardous Substances Data)

Upstream product

• 1273-86-5 1-ferrocenylmethanol 
• 99-88-7 4-Isopropylaniline 

Relevant articles and documents

Iron-catalyzed ferrocenylmethanol OH substitution by S, N, P, and C nucleophiles

The iron complex [Fp][OTf] {Fp+ = [Fe(CO)2(Cp)] +, OTf- = SO3CF3-} is an efficient catalyst for the direct substitution of the OH group in ferrocenylmethanol [Fc-CH2OH] by thiols, aromatic amines, diphenylphosphane, and carbon nucleophiles (furan, pyrrole, and indole). This approach offers a convenient route to ferrocenes containing side chains with different functional groups. The advantages of the method are associated with the use of a catalyst based on iron, which is a nontoxic and readily available transition metal, and in the direct OH substitution, which produces water as the only byproduct. Direct substitution of the OH group in ferrocenylmethanol by S, N, P, and C nucleophiles containing an active hydrogen atom (thiols, aromatic amines, diphenylphosphane, furan, pyrrole, indole) can be accomplished by use of the iron catalyst [Fe(CO)2(Cp)][OTf] (Cp = cyclopentadienyl, OTf = SO3CF3). Copyright