1453864-82-8

Basic information

• Product Name: 1-naphthyl(4’-methoxyphenyl)iodonium tosylate
• Synonyms: 1-naphthyl(4’-methoxyphenyl)iodonium tosylate
• CAS NO: 1453864-82-8
• Molecular Weight: 532.399
• Mol File: 1453864-82-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-naphthyl(4’-methoxyphenyl)iodonium tosylate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-naphthyl(4’-methoxyphenyl)iodonium tosylate(1453864-82-8)
• EPA Substance Registry System: 1-naphthyl(4’-methoxyphenyl)iodonium tosylate(1453864-82-8)

Safety Data

• Hazardous Substances Data: 1453864-82-8(Hazardous Substances Data)

Upstream product

• 90-14-2 1-Iodonaphthalene 
• 104-15-4 toluene-4-sulfonic acid 
• 100-66-3 methoxybenzene 
• 621-23-8 1,2,3-trimethoxybenzene 
• 1357918-84-3 4-bromomethyl(diacetoxyiodo)benzene 

Downstream Products

• 86-57-7 1-Nitronaphthalene 

Relevant articles and documents

One-Pot C?H Functionalization of Arenes by Diaryliodonium Salts

A transition-metal-free, mild, and highly regioselective synthesis of nitroarenes from arenes has been developed. The products are obtained in a sequential one-pot reaction by nitration of iodine(III) reagents with two carbon ligands, which are formed in situ from iodine(I). This novel concept has been extended to formation of aryl azides, and constitutes an important step towards catalytic reactions with these hypervalent iodine reagents. An efficient nitration of isolated diaryliodonium salts has also been developed, and the mechanism is proposed to proceed by a [2,2] ligand coupling pathway.