148-86-7Relevant articles and documents
Palladium supported on functionalized mesoporous silica as an efficient catalyst for Suzuki-Miyaura coupling reaction
Zhang, Guoheng,Wang, Peiyu,Wei, Xiufang
, p. 1188 - 1194 (2013)
Mesoporous SBA-15 was modified with organic functional groups by co-condensation method. The functionalized mesoporous silica can be loaded with palladium and the resulting material used as a catalyst for the Suzuki-Miyaura coupling reactions. Highly dispersed and uniform palladium nanoparticles could be detected using transmission electron microscopy. The Pd-SBA-15 nanocomposite with controlled molar ratio of amino groups to palladium exhibits an excellent catalytic activity and low Pd leaching for the Suzuki-Miyaura coupling reaction. The catalyst can also be reused at least six recycles in air with only a minor loss of activity. Graphical Abstract: Mesoporous SBA-15 was modified with organic functional groups by co-condensation method. The functionalized mesoporous silica can be loaded with palladium and the resulting material used as a catalyst for the Suzuki-Miyaura coupling reactions. Highly dispersed and uniform palladium nanoparticles could be detected using transmission electron microscopy. The Pd-SBA-15 nanocomposite with controlled molar ratio of amino groups to palladium exhibits an excellent catalytic activity and low Pd leaching for the Suzuki-Miyaura coupling reaction. The catalyst can also be reused at least six recycles in air with only a minor loss of activity.[Figure not available: see fulltext.]
A graphdiyne-based carbon material for electroless deposition and stabilization of sub-nanometric Pd catalysts with extremely high catalytic activity
Yang, Liang-Liang,Wang, Hong-Juan,Wang, Juan,Li, Yu,Zhang, Wen,Lu, Tong-Bu
, p. 13142 - 13148 (2019)
The development of sub-nanometric metal particles (1 nm) as advanced heterogeneous catalysts has received considerable interest due to their outstanding catalytic performance, while the synthesis and stabilization of sub-nanometric catalysts (SNCs) without using additional surface capping agents remains a challenge. Herein, we report the synthesis of novel three-dimensional pyrenyl graphdiyne (Pyr-GDY) ultrafine nanofibers (3-10 nm), which can serve as an ideal substrate for electroless deposition and stabilization of Pd SNCs through the terminal uncoupled acetenyl groups in Pyr-GDY, with an average Pd particle size of only 0.83 nm. The as-synthesized Pd/Pyr-GDY composite shows extremely high catalytic activities for the reduction of nitroarenes to arylamines and Suzuki coupling reactions, 300 and 25 times higher than those of commercial Pd/C, respectively. The outstanding catalytic performance can be ascribed to the sub-nanometric Pd particles with a "clean surface", and the unique three-dimensional network structure of Pyr-GDY, being favorable for rapid mass transfer. Our result provides an ideal carbon material for electroless deposition and stabilization of other SNCs with a "clean surface", which will display outstanding catalytic activity for various catalytic reactions.
Direct Acetoxylation of Arenes
Hong Nguyen, Thi Anh,Hou, Duen-Ren
supporting information, p. 8127 - 8131 (2021/08/23)
Acetoxylation of arenes is an important reaction and an unmet need in chemistry. We report a metal-free, direct acetoxylation reaction using sodium nitrate under an anhydrous environment of trifluoroacetic acid, acetic acid, and acetic anhydride. Arenes (31 examples), with oxidation potentials (Eox, in V vs SCE) lower than benzene (2.48 V), were acetoxylated with good yields and regioselectivity. A stepwise, single electron-transfer mechanism is proposed.
Rhodium-Catalyzed Carbonylative Coupling of Alkyl Halides with Phenols under Low CO Pressure
Ai, Han-Jun,Li, Chong-Liang,Wang, Hai,Wu, Xiao-Feng
, p. 5147 - 5152 (2020/05/27)
A rhodium-catalyzed carbonylative transformation of alkyl halides under low pressure of CO has been developed. This robust catalyst system allows using phenols as the carbonylative coupling partner and, meanwhile, exhibits high functional group tolerance and good chemoselectivity. Substrates even with a large steric hindrance group or multiple reaction sites can be selectively converted into the desired products in good to excellent yields. A gram-scale experiment was performed and delivered an almost quantitative amount of the product. Control experiments were performed as well, and a possible reaction mechanism is proposed.
