14811-73-5

Basic information

• Product Name: Methyl 9-ForMylnonanoate
• Synonyms: Methyl 9-ForMylnonanoate;9-Formylnonanoic Acid Methyl Ester;methyl 10-oxodecanoate;Decanoic acid, 10-oxo-, methyl ester
• CAS NO: 14811-73-5
• Molecular Formula: C₁₁H₂₀O₃
• Molecular Weight: 200.2747
• Mol File: 14811-73-5.mol
• Article Data: 44

Chemical Properties

• Boiling Point: 121°C/3mmHg(lit.)
• Appearance: /
• Refractive Index: 1.4400 to 1.4440
• Storage Temp.: Refrigerator
• Solubility: Dichloromethane; Ethyl Acetate; Acetonitrile
• CAS DataBase Reference: Methyl 9-ForMylnonanoate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 9-ForMylnonanoate(14811-73-5)
• EPA Substance Registry System: Methyl 9-ForMylnonanoate(14811-73-5)

Safety Data

• Hazardous Substances Data: 14811-73-5(Hazardous Substances Data)

Usage

General Description

Methyl 9-formylnonanoate (also known as 3,5,5-trimethylhexanal) is an organic compound with the chemical formula C12H24O2. It is a clear, colorless liquid that is commonly used as a fragrance ingredient in the cosmetic and personal care industry. It has a fruity and green odor, making it suitable for use in perfumes, colognes, and other scented products. Methyl 9-formylnonanoate is also used in the food industry as a flavoring agent, adding a fruity and pleasant aroma to various products. It is considered safe for use in these applications and is subject to regulations and guidelines to ensure its safe handling and usage.

Upstream product

• 65157-90-6 methyl 10,10 dimethoxy decanoate 
• 26825-94-5 10-bromodecanoic acid methyl ester 
• 111-81-9 Methyl 10-undecenoate 
• 67-56-1 methanol 
• 32779-22-9 10,11-dihydroxyundecanoic acid 
• 110-42-9 Methyl decanoate 
• 201230-82-2 carbon monoxide 
• 20731-23-1 methyl non-8-enoate 
• 31642-67-8 non-8-enoic acid 
• 5578-80-3 ω-oxydecanocarboxylic acid 
• 149-73-5 trimethyl orthoformate 
• 112-38-9 10-undecenoic acid 
• 50530-12-6 10-bromodecanoic acid 
• 1679-53-4 10-hydroxydecanoic acid 

Downstream Products

• 818-88-2 sebacic acid mono methyl ester 
• 328935-18-8 methyl 10-(4-vinylphenoxy)dodecanoate 
• 328935-20-2 methyl 10-(4-vinylphenoxy)hexadecanoate 
• 328935-17-7 methyl 10-(4-vinylphenoxy)octadecanoate 
• 328935-26-8 methyl 10-(4-vinylphenoxy)docosanoate 
• 86416-30-0 (E/Z)-10-hexadecen-1-ol 
• 72698-30-7 (E/Z)-10-hexadecenal 
• 505-95-3 12-hydroxydodecanoic acid 
• 45037-67-0 decanedial 
• 4567-98-0 dimethyl undecanedioate 
• 1731-84-6 nonanoic acid methyl ester 
• 1374766-75-2 isopropyl 10-(3-chloro-2,6-dihydroxy-5-formyl-4-methylphenyl)decanoate 
• 1374766-74-1 methyl 10-(3-chloro-5-formyl-2,6-dihydroxy-4-methylphenyl)decanoate 

Relevant articles and documents

Amberlyst A 21 as new and efficient surface catalyst for the cleavage of 2-nitrocycloalkanones

Ring cleavage of 2-Nitrocycloalkanones with methanol/Amberlyst A 21 gave methyl ω-nitroalkanoates, O2NCH2(CH2)(n)CO2Me where n = 3-6, 8-10,13, in high yield. Subsequent Nef reaction gave the corresponding ω-oxo compounds which were isolated, in the case of methyl 7-oxoheptanoate and methyl 8-oxooctanoate only, or reduced directly with sodium borohydride to give ω-hydroxyalkanoates. A new formal synthesis of exaltolide (15-pentadecanolide) is also reported.

Ozone: A versatile reagent for solid phase synthesis

Ozone is a versatile reagent which is well adapted to solid phase synthesis: terminal double bonds can he efficiently converted into alcohols, aldehydes or carboxylic acids depending on the reaction conditions.

A ROUTE TO LARGE CARBOCYCLES USING AN ALICYCLIC CLAISEN REARRANGEMENT.

A potentially general route to large carbocycles is described involving a Claisen rearrangement of silyl enolates derived from appropriate unsaturated macrolides.

A new simple synthesis of a prostanoid synthon

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Novel Photooxidation of Alkenes Sensitized by p-Dimethoxybenzene

Photoexcited p-dimethoxybenzene catalyses oxidative cleavage of various alkenes to corresponding carbonyls in the presence of oxygen.

A General Approach to Intermolecular Olefin Hydroacylation through Light-Induced HAT Initiation: An Efficient Synthesis of Long-Chain Aliphatic Ketones and Functionalized Fatty Acids

Herein, an operationally simple, environmentally benign and effective method for intermolecular radical hydroacylation of unactivated substrates by employing photo-induced hydrogen atom transfer (HAT) initiation is described. The use of commercially available and inexpensive photoinitiators (Ph2CO and NHPI) makes the process attractive. The olefin hydroacylation protocol applies to a wide array of substrates bearing numerous functional groups and many complex structural units. The reaction proves to be scalable (up to 5 g). Different functionalized fatty acids, petrochemicals and naturally occurring alkanes can be synthesized with this protocol. A radical chain mechanism is implicated in the process.

DIHYDROOROTIC ACID DEHYDROGENASE INHIBITOR

The present invention provides a novel dihydroorotic acid dehydrogenase inhibitor which is applicable to various diseases. When used as an active ingredient, a compound represented by formula (I): (wherein X represents a halogen atom, R1 represents a hydrogen atom, R2 represents an alkyl group containing 1 to 7 carbon atoms, R3 represents -CHO, and R4 represents -CH2-CH=C(CH3)-R0 (wherein R0 represents an alkyl group containing 1 to 12 carbon atoms which may have a substituent on the terminal carbon and/or on a non-terminal carbon, etc.)), an optical isomer thereof or a pharmaceutically acceptable salt thereof has a high inhibitory effect on dihydroorotic acid dehydrogenase and can be used as an immunosuppressive agent, a therapeutic agent for rheumatism, an anticancer agent, a therapeutic agent for graft rejection, an antiviral agent, an anti-H. pylori agent, a therapeutic agent for diabetes or the like.

Palladium-catalyzed reduction of carboxylic acids to aldehydes with hydrosilanes in the presence of pivalic anhydride

A palladium catalyst system that allows the reduction of carboxylic acids to the corresponding aldehydes with hydrosilanes as reducing agent and pivalic anhydride as an indispensable reagent has been developed. A simple mixture of commercially available bis(dibenzylideneacetone)palladium(0) [Pd(dba) 2], tri(para-tolyl)phosphane and methylphenylsilane realized the reduction of various aliphatic carboxylic acids as well as benzoic acids to aldehydes in good to high yields. Copyright