1485-75-2

Basic information

• Product Name: Cyclohexanamine, N-(benzoyloxy)-
• CAS NO: 1485-75-2
• Molecular Formula: C13H17NO2
• Molecular Weight: 219.283
• Mol File: 1485-75-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Cyclohexanamine, N-(benzoyloxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanamine, N-(benzoyloxy)-(1485-75-2)
• EPA Substance Registry System: Cyclohexanamine, N-(benzoyloxy)-(1485-75-2)

Safety Data

• Hazardous Substances Data: 1485-75-2(Hazardous Substances Data)

Upstream product

• 108-91-8 cyclohexylamine 
• 94-36-0 dibenzoyl peroxide 
• 100-64-1 cyclohexanone-oxime 
• 98-88-4 benzoyl chloride 
• 29456-22-2 cyclohexanone oxime benzoyl ester 

Downstream Products

• 1485-64-9 N-Cyclohexyl-N-benzoyloxy-N'-phenyl-harnstoff 
• 5459-93-8 N-ethyl-cyclohexanamine 
• 1759-68-8 N-benzoylcyclohexylamine 
• 64934-62-9 N-benzoyloxy-N-cyclohexylbenzamide 
• 452303-38-7 L-glutamic acid 5-(N-benzyloxy-N-cyclohexyl)amide 
• 452303-49-0 N²-[4-(N-benzyloxy-N-cyclohexylcarbamoyl)-n-butanoyl]-L-lysine 
• 452303-41-2 N²-[4-(N-benzyloxy-N-cyclohexylcarbamoyl)-n-butanoyl]-N⁶-benzyloxycarbonyl-L-lysine 
• 439152-26-8 N-[N^2',N^6'-bis(2,3-diacetoxybenzoyl)-L-lysyl]-L-glutamic acid 5-(N-benzyloxy-N-cyclohexyl)amide 
• 439152-29-1 N²-[4-(N-benzyloxy-N-cyclohexylcarbamoyl)-n-butanoyl]-N⁶-[N^2',N^6'-bis(2,3-diacetoxybenzoyl)-L-lysyl]-L-lysine 
• 1660-83-9 1-cyclohexyl-1-hydroxy-3-phenyl-urea 
• 1500-28-3 2-cyclohexyl-4-phenyl-[1,2,4]oxadiazolidine-3,5-dione 
• 108-94-1 cyclohexanone 
• 1510821-74-5 2-(2-(cyclohexylamino)phenyl)-5-methyl-1H-pyrazol-3(2H)-one 
• 1510821-80-3 2-(2-(cyclohexylamino)-5-(trifluoromethyl)phenyl)-5-methyl-1H-pyrazol-3(2H)-one 

Relevant articles and documents

Direct N-O bond formation via oxidation of amines with benzoyl peroxide

Herein, we report a general and efficient method for direct N-O bond formation without undesirable C-N bond (amide) formation starting from commercially available amines and benzoyl peroxide. The oxidation of 1,2-diamines to furnish bis-(benzoyloxy)-1,2-diamines is reported for the first time. We found that a significant amount of water (BPO?:?water = 3?:?1) in combination with Cs2CO3 is necessary to achieve high selectivity and yield. The reaction conditions are applicable to a wide range of 1,2-diamine and 1,2-disubstituted-1,2-diamine substrates. Additionally this method is highly applicable to primary and secondary amines. Further, the present method can access chiral bis-hydroxamic acids and bis-hydroxyl amines in just two steps from 1,2-diamines. The reaction conditions are simple, mild and inert atmosphere free. The synthetic potential of this methodology is further demonstrated in the short synthesis of a chiral BHA ligand.

Amide groups switch selectivity: C-H trifluoromethylation of α,β-unsaturated amides and subsequent asymmetric transformation

The first direct C-H β-trifluoromethylation of unsubstituted or α-alkyl-substituted α,β-unsaturated carbonyl compounds under metal-free conditions was realized with excellent regio- and stereoselectivity as well as a very broad substrate scope. Both olefi

Notiz zur Aminolyse von Dibenzoyl-peroxid mit primaeren Aminen

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