15242-79-2

Basic information

• Product Name: bis-1-(phenyl-azo)-2-naphtholatecopper(II)
• Synonyms: bis-1-(phenyl-azo)-2-naphtholatecopper(II)
• CAS NO: 15242-79-2
• Molecular Weight: 558.098
• Mol File: 15242-79-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: bis-1-(phenyl-azo)-2-naphtholatecopper(II)(CAS DataBase Reference)
• NIST Chemistry Reference: bis-1-(phenyl-azo)-2-naphtholatecopper(II)(15242-79-2)
• EPA Substance Registry System: bis-1-(phenyl-azo)-2-naphtholatecopper(II)(15242-79-2)

Safety Data

• Hazardous Substances Data: 15242-79-2(Hazardous Substances Data)

Upstream product

• 142-71-2 copper diacetate 
• 842-07-9 Sudan I 
• 1602-30-8 1-phenyl-azo-2-naphthol 
• 100-34-5 benzene diazonium chloride 
• 135-19-3 β-naphthol 

Downstream Products

• 86-74-8 9H-carbazole 
• 62-53-3 aniline 
• 135-19-3 β-naphthol 

Relevant articles and documents

COPPER(II) IN ORGANIC SYNTHESIS. III. REACTION OF COPPER(II) COMPLEXES OF o-QUINONE MONOPHENYLHYDRAZONES WITH DIMETHYL ACETYLENEDICARBOXYLATE

Bis-copper(II) complexes of o-quinone monophenylhydrazones (2a-e) react with dimethyl acetylenedicarboxylate.Probably through a Michael reaction followed by intramolecular cyclization, o-benzoquinone derivatives 2a,b give indazoles 5a,b, also synthesized by a new route from isatines.Naphtho- and phenanthroquinone derivatives 2c-e are oxidized by copper(II) ions to ketocarbenes which undergo 1,3-dipolar cycloaddition to benzofuran derivatives 11c-e.