15390-25-7Relevant articles and documents
Synthesis and structure of (acetylacetonato-κ2-O,O') (bistriphenylphosphine)palladium tetrafluoroborate as a precursor of catalysts active in the conversion of unsaturated hydrocarbons
Tkach,Suslov,Kurat'Eva,Bykov,Belova
, p. 752 - 756 (2011/11/29)
An X-ray diffraction analysis is carried out for the complex [Pd(Acac)(PPh3)2]BF4 (I), which is a precursor of the active complexes of styrene dimerization and norbornene additive polymerization in the system [(Acac)Pd(PPh3)2]BF 4-BF3 ? OEt2. In complex I the palladium atom is coordinated by two oxygen atoms of the acetylacetonate ligand and two phosphorus atoms of the triphenylphosphine ligands at the vertices of the distorted square.