1576-84-7

Basic information

• Product Name: ACETIC ACID 3-BUTEN-1-YL ESTER
• Synonyms: ACETIC ACID 3-BUTEN-1-YL ESTER;4-ACETOXY-1-BUTENE;3-BUTEN-1-YL ACETATE;2-Vinylethyl acetate;3-Buten-1-ol acetate;3-Butenyl acetate;acetic acid 3-butenyl ester;acetic acid but-3-enyl ester
• CAS NO: 1576-84-7
• Molecular Formula: C₆H₁₀O₂
• Molecular Weight: 114.14
• Mol File: 1576-84-7.mol
• Article Data: 27

Chemical Properties

• Boiling Point: 128 °C
• Flash Point: 34.6°C
• Appearance: /
• Density: 0.91
• Vapor Pressure: 12.6mmHg at 25°C
• Refractive Index: 1.4100-1.4120
• CAS DataBase Reference: ACETIC ACID 3-BUTEN-1-YL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: ACETIC ACID 3-BUTEN-1-YL ESTER(1576-84-7)
• EPA Substance Registry System: ACETIC ACID 3-BUTEN-1-YL ESTER(1576-84-7)

Safety Data

• RIDADR: 3271
• HazardClass: 3
• PackingGroup: III
• Hazardous Substances Data: 1576-84-7(Hazardous Substances Data)

Usage

General Description

Acetic Acid 3-Buten-1-yl Ester, also known as vinyl butyl acetate or 3-butenyl acetate, is an organic chemical compound. It has a molecular formula of C7H12O2 and features a butenyl group attached to the acetic acid ester. This colorless liquid has a pleasant odor and is predominantly used in the flavor and fragrance industry due to its fruity smell that somewhat resembles the aroma of apples or pineapples. Its use extends to food flavoring where it's commonly used to impart apple-like flavors. However, like many chemicals used in these industries, care needs to be taken when handling as it can cause skin and eye irritation, disturbances to the central nervous system, and digestive tract issues when swallowed.

InChI:InChI=1/C6H10O2/c1-3-4-5-8-6(2)7/h3H,1,4-5H2,2H3

Upstream product

• 627-27-0 homoalylic alcohol 
• 56703-55-0 but-3-yn-1-yl acetate 
• 628-67-1 butane-1,4-diol diacetate 
• 1117-31-3 1,3-diacetoxybutane 
• 108-24-7 acetic anhydride 
• 64-19-7 acetic acid 
• 1576-98-3 trans-1,4-diacetoxy-2-butene 
• 75-36-5 acetyl chloride 
• 5162-44-7 1-bromo-4-butene 
• 143314-17-4 1-ethyl-3-methylimidazolium acetate 
• 108-05-4 vinyl acetate 
• 110-88-3 1,3,5-Trioxan 

Downstream Products

• 627-27-0 homoalylic alcohol 
• 106-98-9 1-butylene 
• 3681-82-1 acetic acid hex-3-enyl ester 
• 69182-63-4 diacetoxy-1,6 hexene-3 
• 108794-03-2 (-)-8-phenylmenthyl (2S)-2-hydroxy-6-acetoxy-4-hexenoate 
• 110-63-4 Butane-1,4-diol 
• 18826-95-4 1.3-butanediol 
• 74-85-1 ethene 
• 110211-07-9 3-hydroxy-4-phenylthiobutyl acetate 
• 75668-72-3 N-<(E)-4-(1-Oxoethoxy)-2-butenylsulfinyl>-p-toluolsulfonamid 
• 74608-07-4 N-(1-Acetoxymethylallyl)-N-(p-toluolsulfonamidothio)-p-toluolsulfonamid 
• 116043-36-8 (E)-N-methyl-N-(1-buten-2-yl)-p-toluensulfonamide 
• 116043-37-9 N-methyl-N-(1-vinyl-3-butenyl)-p-toluensulfonamide 
• 97187-36-5 N-methyl-N'-(2,7-octadienyl)-p-toluenesulfamide 

Relevant articles and documents

Synthesis of L-ascorbic acid derivatives as potential bone remodeling agents taking advantage of the Mitsunobu reaction

The synthesis of ascorbic acid derivatives 7a-d is described. Starting from alkenylacetates 1a-d subjected to a hydrosilylation reaction, the resulting hydroxy chloro silanes 3a-d were obtained in high yield. The latter compounds were reacted with potassium phthalimide followed with hydrazine hydrate to give the amino silanols 5a-d. Ascorbic acid was then alkylated on its 3-hydroxy position to give 7a-d by means of a Mitsunobu reaction.

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Developing a Bench-Scale Green Diboration Reaction toward Industrial Application

We report a new methodology for the organocatalytic diboration reaction using inexpensive, sustainable, nontoxic, commercially available halogen salts. This is an educative manuscript for the transformation of laboratory scale reactions into a sustainable approach of appeal to industry.

Enantioselective Hydroformylation of 1-Alkenes with Commercial Ph-BPE Ligand

A rhodium complex, in conjunction with commercially available Ph-BPE ligand, catalyzes the branch-selective asymmetric hydroformylation of 1-alkenes and rapidly generates α-chiral aldehydes. A wide range of terminal olefins including 1-dodecene were examined, and all delivered high enantioselectivity (up to 98:2 er) as well as good branch:linear ratios (up to 15:1). (Chemical Equation Presented).