1609469-10-4Relevant articles and documents
Alkyl transfer from C-C cleavage: Replacing the nitro group of nitro-olefins
Li, Guangxun,Wu, Lei,Lv, Gang,Liu, Hongxin,Fu, Qingquan,Zhang, Xiaomei,Tang, Zhuo
supporting information, p. 6246 - 6248 (2014/06/09)
Alkyl substituted Hantzsch esters are rationally used as alkylation reagents to replace the nitro groups of nitro olefins to give excellent yields of trans-olefins. The reaction mechanism is considered to proceed through a free radical mechanism, which is different from the corresponding transfer alkylation of imines. This journal is the Partner Organisations 2014.