1613320-24-3

Basic information

• Product Name: 6-O-benzoyl-1,2:4,5-di-O-cyclohexylidene-epi-inositol
• Synonyms: 6-O-benzoyl-1,2:4,5-di-O-cyclohexylidene-epi-inositol
• CAS NO: 1613320-24-3
• Molecular Weight: 444.525
• Mol File: 1613320-24-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-O-benzoyl-1,2:4,5-di-O-cyclohexylidene-epi-inositol(CAS DataBase Reference)
• NIST Chemistry Reference: 6-O-benzoyl-1,2:4,5-di-O-cyclohexylidene-epi-inositol(1613320-24-3)
• EPA Substance Registry System: 6-O-benzoyl-1,2:4,5-di-O-cyclohexylidene-epi-inositol(1613320-24-3)

Safety Data

• Hazardous Substances Data: 1613320-24-3(Hazardous Substances Data)

Upstream product

• 1613320-22-1 4-O-benzoyl-2,3:5,6-di-O-cyclohexylidene-epi-inosose 

Downstream Products

• 1613160-46-5 3-O-acetyl-6-O-benzoyl-1,2:4,5-di-O-cyclohexylidene-epi-inositol 

Relevant articles and documents

Bio-inspired synthesis of rare and unnatural carbohydrates and cyclitols through strain driven epimerization

We report a bio-inspired, strain driven epimerization of trans-ketals to cis-ketals through an enolate intermediate. Swern oxidation of a hydroxyl group adjacent to a trans-ketal effects both oxidation and its epimerization to cis-ketal. This novel and general strategy allows inversion of up to three contiguous stereocenters and has been illustrated by the synthesis of several unnatural/rare isomers of carbohydrates/cyclitols from their naturally abundant isomers. This journal is the Partner Organisations 2014.