16178-87-3

Basic information

• Product Name: Cyclohexanone, 2-methyl-2-(2-propenyl)-
• CAS NO: 16178-87-3
• Molecular Formula: C10H16O
• Molecular Weight: 152.236
• Mol File: 16178-87-3.mol
• Article Data: 27

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-methyl-2-(2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-methyl-2-(2-propenyl)-(16178-87-3)
• EPA Substance Registry System: Cyclohexanone, 2-methyl-2-(2-propenyl)-(16178-87-3)

Safety Data

• Hazardous Substances Data: 16178-87-3(Hazardous Substances Data)

Upstream product

• 583-60-8 2-Methylcyclohexanone 
• 1196-73-2 1-acetoxy-2-methylcyclohexene 
• 106-95-6 allyl bromide 
• 32116-69-1 2-n-Butylthiomethylen-cyclohexanon 
• 591-87-7 Allyl acetate 
• 21750-52-7 1-tri-n-butylstannyloxy-2-methylcyclohex-1-ene 
• 35466-83-2 allyl methyl carbonate 
• 19980-35-9 1-trimethylsilyloxy-2-methyl-1-cyclohexene 
• 29443-23-0 N,N,N-triethylprop-2-en-1-aminium bromide 
• 86950-89-2 allyl (2-methylcyclohex-1-en-1-yl)carbonate 
• 100747-79-3 N-allyl-N-phenyl-2-methyl-1-cyclohexenylamine 
• 87394-33-0 N'-[3-Allyl-3-methyl-2-oxo-cyclohex-(E)-ylidene]-hydrazinecarboxylic acid methyl ester 
• 7770-41-4 1-methyl-2-oxocyclohexanecarboxylic acid 2-propenyl ester 
• 107-18-6 allyl alcohol 

Downstream Products

• 217969-86-3 2-methyl-2-propyl-cyclohexanone 
• 861618-11-3 2-Allyl-2-methyl-cyclohexanol 
• 57620-47-0 2-allyl-2-methyl-cyclohexanone oxime 
• 78707-66-1 2-Allyl-1-benzenesulfinylmethyl-2-methyl-cyclohexanol 
• 131581-11-8 (E)-<2'-methyl-2'-(prop-2''-enyl)cyclohexylidene>acetonitrile 
• 105643-70-7 (1-Methyl-2-oxo-cyclohexyl)-acetaldehyde 
• 131581-04-9 <2'-methyl-2'-(prop-2''-enyl)cyclohexylidene>propanedinitrile 
• 58711-31-2 (1-methyl-2-oxo-cyclohexyl)-acetic acid 
• 64-18-6 formic acid 
• 277307-93-4 2-(diethoxy-phosphoryl)-4-ethoxythiocarbonylsulfanyl-5-(1-methyl-2-oxo-cyclohexyl)-pentanoic acid ethyl ester 
• 78707-63-8 3-Allyl-3-methyl-2-methylene-cyclohexanone 

Relevant articles and documents

PALLADIUM-CATALYZED ALLYLATION OF KETONES AND ALDEHYDES VIA ALLYL ENOL CARBONATES

Rearrangement of allyl enol carbonates, prepared from ketones or aldehydes by trapping their enolates with allyl chloroformate, to give α-allyl ketones or aldehydes regioselectively is catalyzed by palladium-phosphine complexes under mild conditions.

SYNTHESIS OF γ,δ-UNSATURATED KETONES BY THE INTRAMOLECULAR DECARBOXYLATIVE ALLYLATION OF ALLYL β-KETO CARBOXYLATES AND ALKENYL ALLYL CARBONATES CATALYZED BY MOLYBDENUM, NICKEL, AND RHODIUM COMPLEXES

Allyl β-keto carboxylates and alkenyl allyl carbonates were converted to γ,δ-unsaturated ketones by the intramolecular decarboxylative allylation catalyzed by molybdenum, nickel, and rhodium complexes.

Selective Synthesis of Cyclooctanoids by Radical Cyclization of Seven-Membered Lactones: Neutron Diffraction Study of the Stereoselective Deuteration of a Chiral Organosamarium Intermediate

Seven-membered lactones undergo selective SmI2–H2O-promoted radical cyclization to form substituted cyclooctanols. The products arise from an exo-mode of cyclization rather than the usual endo-attack employed in the few radical syntheses of cyclooctanes. The process is terminated by the quenching of a chiral benzylic samarium. A labeling experiment and neutron diffraction study have been used for the first time to probe the configuration and highly diastereoselective deuteration of a chiral organosamarium intermediate.

Enantioselective, catalytic allylation of ketones and olefins

Compounds containing a substituted or unsubstituted allyl group directly bound to a chiral carbon atom are prepared enantioselectively. Starting reactants are either chiral or achiral, and may or may not contain an attached allyloxycarbonyl group as a sub