1647-85-4

Basic information

• Product Name: Peroxide, bis[4-(trifluoromethyl)benzoyl]
• CAS NO: 1647-85-4
• Molecular Formula: C16H8F6O4
• Molecular Weight: 378.228
• Mol File: 1647-85-4.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Peroxide, bis[4-(trifluoromethyl)benzoyl](CAS DataBase Reference)
• NIST Chemistry Reference: Peroxide, bis[4-(trifluoromethyl)benzoyl](1647-85-4)
• EPA Substance Registry System: Peroxide, bis[4-(trifluoromethyl)benzoyl](1647-85-4)

Safety Data

• Hazardous Substances Data: 1647-85-4(Hazardous Substances Data)

Upstream product

• 329-15-7 4-trifluoromethyl-phenyl acetyl chloride 
• 455-24-3 4-trifluoromethylbenzoic acid 

Downstream Products

• 118437-18-6 4-Trifluormethylbenzoyloxyl-Radikal 
• 675201-52-2 Pd(O₂CC₆H₄CF₃)2(N,N,N',N'-tetramethylethylenediamine) 
• 212697-76-2 Pd(O₂CPh)2(2,2'-bipyridine) 
• 91888-96-9 N-(tert-butyl)-4-(trifluoromethyl)benzamide 
• 880493-15-2 6-(4-(trifluoromethyl)phenyl)phenanthridine 
• 1174895-53-4 2-(4′-(trifluoromethyl)-[1,1′-biphenyl]-2-yl)pyridine 

Relevant articles and documents

Aryl acyl peroxides for visible-light induced decarboxylative arylation of quinoxalin-2(1: H)-ones under additive-, metal catalyst-, and external photosensitizer-free and ambient conditions

Aryl radicals were generated for the first time from cheap and easily available aryl acyl peroxides in eco-friendly ethyl acetate under ambient conditions and visible-light illumination in the absence of any additive, metal catalyst, or external photosensitizer. The present arylation of quinoxalin-2(1H)-ones was chemo- and regioselective, and provided good access to various 3-arylquinoxalin-2(1H)-ones. This journal is

An unprecedented cobalt-catalyzed selective aroylation of primary amines with aroyl peroxides

A novel and facile cobalt-catalyzed selective aroylation of primary amines with aroyl peroxides was developed for the synthesis of aryl amides. It was unprecedented that C[sbnd]N bond formation product was selectively generated without the common N[sbnd]O bond formation product. Aroyl peroxides act as the sole aroylation reagent without additional base or oxidant. The reactions proceeded under mild conditions and showed broad substrates scope with a series of primary amines and aroyl peroxides.

Palladium(II)-catalyzed othro-C-H-benzoxylation of 2-arylpyridines by oxidative coupling with aryl acylperoxides

A palladium(II)-catalyzed ortho-benzoxylation of 2-arylpyridines with aryl acylperoxides was developed. With pyridyl as directing group, the benzoxylation reaction exhibits remarkable regioselectivity and excellent functional group tolerance, providing the products in up to 87% yield.