1650-20-0Relevant articles and documents
Constructing the CF3 group; Unique trifluorodecarboxylation induced by BrF3
Sasson, Revital,Rozen, Shlomo
, p. 1083 - 1086 (2007/10/03)
A variety of 2-alkyl-1,3-dithiane-2-carboxylic acids was prepared from the appropriate alkyl halides, 1,3-dithiane and CO2. These acids were reacted with BrF3 to form the trifluoromethylalkyl derivatives via a combination of ionic and radical trifluorodecarboxylation in about 50-60% yield.