19043-23-3Relevant articles and documents
Calcined and silylated K10 montmorillonites as catalysts of pericyclic reactions of trans-anethole
Fraile,Garcia,Mayoral,Tarnai,Alonso
, p. 1981 - 1982 (1996)
Cation-exchanged K10 montmorillonites are calcined and silylated in order to eliminate acid sites. The solids obtained promote the Diels-Alder reaction of cyclopentadiene with trans-anethole and the cyclodimerization of trans-anethole.
Cation Radical Catalyzed Olefin Cyclodimerization
Bauld, Nathan L.,Pabon, Raul
, p. 633 - 634 (1983)
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Anethole isomerization and dimerization induced by acid sites or UV irradiation
Castro, Hans T.,Martinez, Jairo Rene,Stashenko, Elena
experimental part, p. 5012 - 5030 (2010/10/21)
The formation of cis-anethole and various dimers as a result of the exposure of trans-anethole to microporous solid acids (dealuminated HY zeolites), or UV-Vis irradiation was established by means of high resolution gas chromatography coupled to mass spectrometry. 3,4-bis-(4-Methoxyphenyl)-(E)-hex- 2-ene was the most abundant compound among eight different methoxyphenyl- disubstituted hexenes produced by electrophilic addition and elimination reactions induced by HY zeolites. (1a,2a,3b,4b)-1,2-bis(4-Methoxyphenyl)-3,4- dimethylcyclobutane was the principal component in the mixture of 5 methoxyphenyl-disubstituted cyclobutanes found, together with cis-anethole, after UV-Vis irradiation of a trans-anethole solution in toluene.