194922-77-5Relevant articles and documents
An external chiral ligand controlled enantioselective opening of oxirane and oxetane by organolithiums
Mizuno, Masashi,Kanai, Motomu,Iida, Akira,Tomioka, Kiyoshi
, p. 10699 - 10708 (1997)
Enantioselective nucleophilic opening reactions of cyclohexene oxide and 3-phenyloxetane were achieved by the combination of an external chiral ligand and organolithiums in the presence of boran trifluoride to give the corresponding alcohols in up to 47% ee.