19657-56-8

Basic information

• Product Name: dibenzyl hyponitrite
• Synonyms: dibenzyl hyponitrite
• CAS NO: 19657-56-8
• Molecular Weight: 242.277
• Mol File: 19657-56-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dibenzyl hyponitrite(CAS DataBase Reference)
• NIST Chemistry Reference: dibenzyl hyponitrite(19657-56-8)
• EPA Substance Registry System: dibenzyl hyponitrite(19657-56-8)

Safety Data

• Hazardous Substances Data: 19657-56-8(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 620-05-3 iodomethylbenzene 

Downstream Products

• 588-64-7 benzaldehyde phenylhydrazone 
• 100-51-6 benzyl alcohol 
• 100-52-7 benzaldehyde 
• 2291-96-5 triethyl(benzyloxy)stannane 

Relevant articles and documents

Aminopyridine-Borane Complexes as Hydrogen Atom Donor Reagents: Reaction Mechanism and Substrate Selectivity

Lewis base-borane complexes are shown to be potent hydrogen atom donors in radical chain reduction reactions. Results obtained in 1H, 11B, and 13C NMR measurements and kinetic experiments support a complex reaction mechanism involving the parent borane as well as its initial reaction products as active hydrogen atom donors. Efficient reduction reactions of iodides, bromides, and xanthates in apolar solvents rely on initiator systems generating oxygen-centered radicals under thermal conditions and pyridine-borane complexes carrying solubilizing substituents. In contrast to tin hydride reagents, the pyridine-boranes reduce xanthates faster than the corresponding iodides.