23010-53-9

Basic information

• Product Name: Boc-Ile-Lys(Z)-OMe
• Synonyms: Boc-Ile-Lys(Z)-OMe
• CAS NO: 23010-53-9
• Molecular Weight: 507.627
• Mol File: 23010-53-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Boc-Ile-Lys(Z)-OMe(CAS DataBase Reference)
• NIST Chemistry Reference: Boc-Ile-Lys(Z)-OMe(23010-53-9)
• EPA Substance Registry System: Boc-Ile-Lys(Z)-OMe(23010-53-9)

Safety Data

• Hazardous Substances Data: 23010-53-9(Hazardous Substances Data)

Upstream product

• 55355-50-5 N^ω-benzyloxycarbonyl-(RS)-lysine methyl ester hydrochloride 
• 66866-47-5 C₁₆H₂₉NO₆ 
• 13139-16-7 N-(t-butoxycarbonyl)-isoleucine 
• 24498-31-5 (S)-methyl 2-amino-6-(benzyloxycarbonylamino)hexanoate 
• 13139-16-7 N-tert-butyloxy-isoleucine 
• 27894-50-4 methyl (2S)-2-amino-6-{[(benzyloxy)carbonyl]amino}hexanoate hydrochloride 
• 66866-47-5 Boc-Ile-O-COOiBu 
• 98807-35-3 Boc-Ile-O-COOtBu 
• 543-27-1 isobutyl chloroformate 
• 13139-16-7 N-(tert-butyloxycarbonyl)-L-isoleucine 
• 24424-99-5 di-tert-butyl dicarbonate 

Downstream Products

• 23010-54-0 Boc-Ileu-(N^ε-Z-Lys) 

Relevant articles and documents

THE PREPARATION AND REACTIONS OF MIXED ANHYDRIDES OF N-ALKOXYCARBONYLAMINO ACIDS

Pure mixed anhydrides R1OCO-Xxx-O-COOR2 (Xxx=NHCHRCO) have been obtained by reaction of N-alkoxycarbonylamino acids R1OCO-Xxx-OH with alkyl chloroformate R2OCOCl (R2=methyl, ethyl, isobutyl, menthyl)

Mixed Anhydrides in Peptide Synthesis. Reduction of Urethane Formation and Racemization Using N-Methylpiperidine as the Tertiary Amine Base

The side reactions of urethane formation and racemization accompanying couplings by the mixed anhydride method are reduced when N-methylpiperidine is used as base, the best results being achieved in dichloromethane.