234430-13-8

Basic information

• Product Name: 2-diphenylphosphinopicolinamide
• CAS NO: 234430-13-8
• Molecular Weight: 306.304
• Mol File: 234430-13-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-diphenylphosphinopicolinamide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-diphenylphosphinopicolinamide(234430-13-8)
• EPA Substance Registry System: 2-diphenylphosphinopicolinamide(234430-13-8)

Safety Data

• Hazardous Substances Data: 234430-13-8(Hazardous Substances Data)

Upstream product

• 98-92-0 nicotinamide 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 364631-06-1 [(η5-pentamethylcyclopentadienyl)rhodium(III)Cl2(3-NC5H4C(O)NHP(C6H5)2)] 
• 364631-10-7 cis-[(3-NC₅H₄C(O)NHP(C₆H₅)2)2platinum(II)Cl₂] 
• 364631-08-3 [(η6-p-cymene)(3-NC5H4C(O)NHP(C6H5)2)ruthenium(II)Cl2] 

Relevant articles and documents

Spectroscopic and structural characterization of O,O′-(diphenylphosphineoxide)amidate and acetylacetonate complexes of pentacoordinate nickel(II)

Heteroleptic nickel pentacoordinate complexes with the macrocyclic ligands 2,4,4-trimethyl-1,5,9-triazacyclododec-1-ene (Me3-mcN3) or its 9-methyl derivative (Me4-mcN3), as ancillary ligands, and O,O′-(diphenylphosphineoxide)amidate ligands, [RC(O)NP(O)Ph2]? (R = C6H6 (1), C5H4N (2), C4H3S (3)), have been prepared as well as related acetylacetonate derivatives. The complexes have been studied by spectroscopic methods (IR, UV-Vis and 1H NMR). In acetone solution, the complexes exhibit isotropically shifted 1H NMR resonances. The full assignment of these resonances has been achieved using one- and two-dimensional 1H NMR techniques. The single-crystal structures of {(Me4-mcN3)Ni[OP(Ph2)NC(Tf)O]}[PF6] (9) and {(Me3-mcN3)Ni(acac)}[PF6] (10) have been established by X-ray diffraction.